Department of Analytical Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Sklodowska University, M. C. Sklodowska Sq. 3, 20-031 Lublin, Poland.
Institute of Environmental Technology, Centre for Energy and Environmental Technologies, VŠB-Technical University of Ostrava, 17. listopadu 15/2172, 708 00 Ostrava, Czech Republic.
Int J Mol Sci. 2023 Jun 29;24(13):10868. doi: 10.3390/ijms241310868.
Chicken cartilage was used for the first time as a raw material for the microwave-assisted synthesis of biochar and activated carbon. Various microwave absorbers, i.e., commercial active carbon, scrap tyres, silicon carbide, and chicken bone-derived biochar, as well as various microwave powers, were tested for their effect on the rate of pyrolysis and the type of products formed. Biochars synthesised under 400 W in the presence of scrap tyres and chicken bone-derived biochar were activated with KOH and KCO with detergent to produce activated carbon with a highly developed porous structure that would be able to effectively adsorb xylene vapours. All carbons were thoroughly characterised (infrared spectroscopy, X-ray fluorescence spectrometry, nitrogen adsorption/desorption, Raman spectroscopy, proximate and ultimate analysis) and tested as xylene sorbents in dynamic systems. It was found that the activation causes an increase of up to 1042 m·g in the specific surface area, which ensures the sorption capacity of xylene about 300 mg·g. Studies of the composition of biogas emitted during pyrolysis revealed that particularly valuable gaseous products are formed when pyrolysis is carried out in the presence of silicon carbide as a microwave absorber.
鸡软骨首次被用作微波辅助合成生物炭和活性炭的原料。研究了各种微波吸收剂,如商业活性炭、废轮胎、碳化硅和鸡骨衍生的生物炭,以及不同的微波功率,以测试它们对热解速率和产物类型的影响。在 400 W 下,在废轮胎和鸡骨衍生的生物炭存在的情况下合成的生物炭,用 KOH 和 KCO 与洗涤剂进行活化,生成具有高度发达的多孔结构的活性炭,能够有效地吸附二甲苯蒸气。所有的碳都经过了彻底的表征(红外光谱、X 射线荧光光谱、氮气吸附/解吸、拉曼光谱、工业分析和元素分析),并在动态系统中作为二甲苯吸附剂进行了测试。结果发现,活化导致比表面积增加了 1042 m·g,这确保了二甲苯的吸附容量约为 300 mg·g。对热解过程中生物气组成的研究表明,当使用碳化硅作为微波吸收剂进行热解时,会形成特别有价值的气态产物。