Rasool Shafket, Kim Jin Young
Graduate School of Carbon Neutrality, School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology, Ulsan 44919, South Korea.
Phys Chem Chem Phys. 2023 Jul 26;25(29):19337-19357. doi: 10.1039/d3cp02591h.
In the search for alternate green energy sources to offset dependence on fossil fuels, solar energy can certainly meet two needs with one deed: fulfil growing global energy demands due to its non-depletable nature and lower greenhouse gas emissions. As such, third generation thin film photovoltaic technology based organic solar cells (OSCs) can certainly play their role in providing electricity at a competing or lower cost than 1st and 2nd generation solar technologies. As OSCs are still at an early stage of research and development, much focus has been placed on improving power conversion efficiencies (PCEs) inside a controlled environment a glove-box (GB) filled with an inert gas such as N. This was necessary until now, to control and study the local nanomorphology of the spin-coated blend films. For OSCs to compete with other solar energy technologies, OSCs should produce similar or even better morphologies in an open environment air, such that air-processed OSCs can result in similar PCEs in comparison to their GB-processed counterparts. In this review, we have compared GB- . air-processed OSCs from morphological and device physics aspects and underline the key features of efficient OSCs, processed in either GB or air.
在寻找替代绿色能源以减少对化石燃料的依赖的过程中,太阳能无疑可以一举两得:因其不可耗尽的特性满足全球不断增长的能源需求,并降低温室气体排放。因此,基于第三代薄膜光伏技术的有机太阳能电池(OSC)肯定能在以与第一代和第二代太阳能技术竞争或更低的成本提供电力方面发挥作用。由于OSC仍处于研发的早期阶段,很多注意力都集中在在充满惰性气体(如氮气)的手套箱(GB)这种受控环境中提高功率转换效率(PCE)。直到现在,这对于控制和研究旋涂混合膜的局部纳米形态来说都是必要的。为了使OSC能与其他太阳能技术竞争,OSC应该在开放环境(空气)中产生相似甚至更好的形态,这样与在手套箱中制备的OSC相比,在空气中制备的OSC能产生相似的PCE。在这篇综述中,我们从形态学和器件物理方面比较了在手套箱中制备的和在空气中制备的OSC,并强调了在手套箱或空气中制备的高效OSC的关键特性。