Wang Xiangyu, Xing Xiaofei, Zhu Hongsong, Li Jing, Liu Tong
Key Laboratory of Aerospace Materials and Performance, Ministry of Education, School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191, PR China.
Key Laboratory of Aerospace Materials and Performance, Ministry of Education, School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191, PR China.
Adv Colloid Interface Sci. 2023 Aug;318:102960. doi: 10.1016/j.cis.2023.102960. Epub 2023 Jul 13.
At present, to solve the threat of electromagnetic wave (EMW) radiation pollution to human health, intelligent control and information security, tremendous efforts have been made to manufacture EMW absorbing materials. For ideal microwave absorption materials (MAMs), it is generally necessary not only to pursue strong microwave absorption (MA) over wide effective absorption bandwidth (EAB), but also to take into account the requirements of light weight, thin matching thickness and chemical stability characteristics. It has been found that magnetite (FeO) is the most promising MAM to absorb and dissipate EMW among various absorbers, because of its good mechanical and chemical stability, controllable morphology, high Curie temperature, easy preparation, economy and excellent magnetic properties. However, the application performance of FeO absorber with single composition is limited by its easy agglomeration, eddy current, high density, and impedance mismatch. In addition, achieving efficient MA metrics with low absorber loading remains a huge challenge. To overcome these limitations, conjugation with dielectric carbon-based materials and special structural designs have been extensively explored as viable solutions to optimize the microwave absorption performance (MAP) of FeO. This paper reviews the recent research progress of FeO/carbon MAMs, and then the influence of dimensions and structures regulations on the MAPs are introduced in detail. Finally, the current existing problems and future development direction of FeO/carbon composites in the field of MA are also presented.
目前,为了解决电磁波(EMW)辐射污染对人类健康、智能控制和信息安全的威胁,人们在制造吸波材料方面付出了巨大努力。对于理想的微波吸收材料(MAM),通常不仅要在宽有效吸收带宽(EAB)上追求强微波吸收(MA),还要考虑轻质、薄匹配厚度和化学稳定性等特性。研究发现,在各种吸收剂中,磁铁矿(FeO)是最有前途的吸收和耗散EMW的MAM,因为它具有良好的机械和化学稳定性、可控的形态、高居里温度、易于制备、经济性和优异的磁性。然而,单一成分的FeO吸收剂的应用性能受到其易团聚、涡流、高密度和阻抗失配的限制。此外,在低吸收剂负载下实现高效的MA指标仍然是一个巨大的挑战。为了克服这些限制,与介电碳基材料的共轭和特殊结构设计已被广泛探索,作为优化FeO微波吸收性能(MAP)的可行解决方案。本文综述了FeO/碳MAM的最新研究进展,然后详细介绍了尺寸和结构调控对MAP的影响。最后,还介绍了FeO/碳复合材料在MA领域目前存在的问题和未来的发展方向。