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热释光剂量计(TLD)研究 CaK(PO ):Dy 荧光粉在辐射剂量学中的应用。

Thermoluminescence dosimeter (TLD) studies of Ca K(PO ) :Dy phosphor for applications in radiation dosimetry.

机构信息

Department of Physics, Dr. B R Ambedkar National Institute of Technology Jalandhar, Jalandhar, India.

P.G. Department of Physics and Electronics, DAV College Amritsar, Amritsar, India.

出版信息

Luminescence. 2023 Oct;38(10):1780-1788. doi: 10.1002/bio.4564. Epub 2023 Aug 21.

Abstract

This study reports the thermoluminescence (TL) aspects of Ca K(PO ) :Dy phosphor synthesized using a wet chemical method for the first time. The X-ray diffraction (XRD) results confirm the formation of the desired crystalline phase. Surface morphological studies reveal the formation of polyhedrons and agglomerations having an average diameter of 200 nm, while energy dispersive X-ray spectroscopy (EDS) data show the presence and composition of the elements in appropriate amounts. The effect of Dy doping concentration has been studied on the TL properties with exposure to gamma radiations from the Co-60 source. The best TL response has been observed for 5 mol% Dy doping concentration. The glow curve is simple and consists of a single peak at 130°C. The effect of the heating rate has been studied on the TL glow curve, and the heating rate of 5°C/s shows the best TL response. The various TL properties such as annealing conditions, dose-response, TL linearity, fading, and reusability of the prepared phosphor have been studied to check its suitability as a good TL dosimeter (TLD). TL characterization of the phosphor reports that the TL response is linear from 5- to 2000 Gy. The results show that this phosphor can be a good TLD for the dosimetry of gamma radiations from Co-60.

摘要

本研究首次报道了采用湿法化学合成的 CaK(PO ) :Dy 荧光粉的热释光(TL)特性。X 射线衍射(XRD)结果证实了所需结晶相的形成。表面形貌研究表明形成了具有 200nm 平均直径的多面体和团聚体,而能谱(EDS)数据表明存在适量的元素及其组成。研究了 Dy 掺杂浓度对 Co-60 源γ辐射暴露下 TL 性能的影响。在 5mol%Dy 掺杂浓度下观察到最佳的 TL 响应。发光曲线简单,由 130°C 处的单个峰组成。研究了加热速率对 TL 发光曲线的影响,5°C/s 的加热速率显示出最佳的 TL 响应。研究了制备的荧光粉的各种 TL 特性,如退火条件、剂量响应、TL 线性度、退色和可重复性,以检查其作为良好 TL 剂量计(TLD)的适用性。荧光粉的 TL 特性表明,TL 响应在 5-2000Gy 范围内呈线性。结果表明,该荧光粉可作为 Co-60 伽马辐射剂量计的良好 TLD。

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