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用于从废水中去除重金属的纳滤膜的最新进展:综述

Recent Advances in Membranes Used for Nanofiltration to Remove Heavy Metals from Wastewater: A Review.

作者信息

Covaliu-Mierlă Cristina Ileana, Păunescu Oana, Iovu Horia

机构信息

Faculty of Biotechnical Systems Engineering, University Politehnica of Bucharest, 313 Splaiul Independentei, 060042 Bucharest, Romania.

Advanced Polymer Materials Group, Faculty of Chemical Engineering and Biotechnologies, University Politehnica of Bucharest, 132 Calea Grivitei, 010737 Bucharest, Romania.

出版信息

Membranes (Basel). 2023 Jul 4;13(7):643. doi: 10.3390/membranes13070643.

Abstract

The presence of heavy metal ions in polluted wastewater represents a serious threat to human health, making proper disposal extremely important. The utilization of nanofiltration (NF) membranes has emerged as one of the most effective methods of heavy metal ion removal from wastewater due to their efficient operation, adaptable design, and affordability. NF membranes created from advanced materials are becoming increasingly popular due to their ability to depollute wastewater in a variety of circumstances. Tailoring the NF membrane's properties to efficiently remove heavy metal ions from wastewater, interfacial polymerization, and grafting techniques, along with the addition of nano-fillers, have proven to be the most effective modification methods. This paper presents a review of the modification processes and NF membrane performances for the removal of heavy metals from wastewater, as well as the application of these membranes for heavy metal ion wastewater treatment. Very high treatment efficiencies, such as 99.90%, have been achieved using membranes composed of polyvinyl amine (PVAM) and glutaraldehyde (GA) for Cr removal from wastewater. However, nanofiltration membranes have certain drawbacks, such as fouling of the NF membrane. Repeated cleaning of the membrane influences its lifetime.

摘要

污染废水中重金属离子的存在对人类健康构成严重威胁,因此进行妥善处理极为重要。由于纳滤(NF)膜运行高效、设计灵活且成本低廉,利用其去除废水中的重金属离子已成为最有效的方法之一。由先进材料制成的纳滤膜因其能够在各种情况下净化废水而越来越受欢迎。事实证明,通过界面聚合、接枝技术以及添加纳米填料来调整纳滤膜的性能,以有效去除废水中的重金属离子,是最有效的改性方法。本文综述了用于去除废水中重金属的改性工艺和纳滤膜性能,以及这些膜在重金属离子废水处理中的应用。使用由聚乙烯胺(PVAM)和戊二醛(GA)组成的膜从废水中去除铬,已实现了99.90%这样非常高的处理效率。然而,纳滤膜存在某些缺点,如纳滤膜的污染。反复清洗膜会影响其使用寿命。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ec7a/10385156/562e7c555e6e/membranes-13-00643-g001.jpg

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