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氯化镁负载对甘蓝基生物炭产率和性能的影响。

Effect of MgCl Loading on the Yield and Performance of Cabbage-Based Biochar.

作者信息

Zhu Cui, Huang Kuncheng, Xue Mengyuan, Zhang Yiming, Wang Jiaquan, Liu Lu

机构信息

School of Mechanical Engineering, Hefei University of Technology, Hefei 230009, China.

Anhui Jincheng Anhuan Technology Development Co., Ltd., Hefei 230000, China.

出版信息

Bioengineering (Basel). 2023 Jul 15;10(7):836. doi: 10.3390/bioengineering10070836.

Abstract

Converting more CO absorbed by plant photosynthesis into biomass-activated carbon effectively reduces carbon emissions. In this study, we used a one-step preparation of biomass-activated carbon loaded with MgO nanoparticles to investigate the effect of Mg loading on the catalytic pyrolysis process. The influences of magnesium loading on biochar yield and fixed carbon production were assessed. The addition of 1% Mg weakened the carbonyl C=O, inhibited the dehydroxylation reaction, enhanced the C-H signal strength, and the formation of MgO inhibited the weaker- bound substituent breakage. Additionally, the addition of magnesium altered the morphological features and chemical composition of the biochar material. It also increased the activated carbon mesoporosity by 3.94%, biochar yield by 5.55%, and fixed carbon yield by 12.14%. The addition of 1% Mg increased the adsorption capacity of the activated carbon to potassium dichromate, acid magenta, methylene blue, and tetracycline effluents by 8.71 mg, 37.15 mg, 117.68 mg, and 3.53 mg, respectively. The results showed that MgCl played a significant role in promoting the thermal degradation of biomass and improving the solid yield and adsorption performance of activated carbon.

摘要

将植物光合作用吸收的更多二氧化碳转化为生物质活性炭可有效减少碳排放。在本研究中,我们采用一步法制备负载氧化镁纳米颗粒的生物质活性炭,以研究镁负载量对催化热解过程的影响。评估了镁负载量对生物炭产率和固定碳生成的影响。添加1%的镁削弱了羰基C=O,抑制了脱羟基反应,增强了C-H信号强度,并且氧化镁的形成抑制了较弱键合取代基的断裂。此外,镁的添加改变了生物炭材料的形态特征和化学成分。它还使活性炭的中孔率提高了3.94%,生物炭产率提高了5.55%,固定碳产率提高了12.14%。添加1%的镁使活性炭对重铬酸钾、酸性品红、亚甲基蓝和四环素废水的吸附容量分别增加了8.71 mg、37.15 mg、117.68 mg和3.53 mg。结果表明,MgCl在促进生物质热降解以及提高活性炭的固体产率和吸附性能方面发挥了重要作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3cb9/10376308/43c305872083/bioengineering-10-00836-g001.jpg

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