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通过使用基于二硫化钼和碳纳米管的先进发动机油纳米添加剂来减少颗粒物排放。

Reducing particulate emissions by using advanced engine oil nanoadditives based on molybdenum disulfide and carbon nanotubes.

作者信息

Bojarska Zuzanna, Goławska Weronika, Mazurkiewicz-Pawlicka Marta, Makowski Łukasz

机构信息

Faculty of Chemical and Process Engineering, Warsaw University of Technology, Waryńskiego 1, 00-645, Warsaw, Poland.

出版信息

Sci Rep. 2023 Aug 21;13(1):13621. doi: 10.1038/s41598-023-39933-6.

Abstract

Nanoadditives can be used to enhance lubricating properties of engine oils. Although many additives have been developed, molybdenum disulfide and carbon nanotubes have attracted significant attention. In this study, we demonstrate that hybrid nanostructures based on these unique materials (MoS/CNTs) positively affect engine oil lubricating properties. Hybrid nanostructures were produced via wet chemical synthesis in impinging jet reactor. This method is characterized by easy scalability and possible continuous operation, which are crucial in material commercialization. The application of 0.5 wt% suspension exhibited the best results, reducing the friction coefficient at the engine operating temperature by up to 26%. Nanoadditives protected the lubricated parts, causing their wear to be considerably lower than the base oil. The effect of nanoadditives on the quality of exhaust gases was also investigated, which has not yet been researched. The application of the oil with MoS/CNT reduced the emissions of solid particles in the gasoline engine exhaust gas. The total volume of particles in the exhaust gas was reduced by 91% and 49% under idling and load-running conditions. This research showed that MoS/CNTs can be successfully used as nanoadditives in engine oils for improving tribological properties, enhancing anti-wear performance, and reducing particle emissions in exhaust gas.

摘要

纳米添加剂可用于增强发动机油的润滑性能。尽管已经开发出许多添加剂,但二硫化钼和碳纳米管已引起了广泛关注。在本研究中,我们证明基于这些独特材料(MoS/CNTs)的混合纳米结构对发动机油的润滑性能有积极影响。混合纳米结构是通过在撞击流反应器中进行湿化学合成制备的。该方法具有易于扩展和可能连续操作的特点,这在材料商业化中至关重要。0.5 wt%悬浮液的应用显示出最佳效果,在发动机工作温度下摩擦系数降低高达26%。纳米添加剂保护了润滑部件,使其磨损远低于基础油。还研究了纳米添加剂对废气质量的影响,这方面尚未有研究。含MoS/CNT的机油应用减少了汽油发动机废气中固体颗粒的排放。在怠速和负载运行条件下,废气中颗粒的总体积分别减少了91%和49%。本研究表明,MoS/CNTs可成功用作发动机油中的纳米添加剂,以改善摩擦学性能、增强抗磨性能并减少废气中的颗粒排放。

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