Seddon Alistair W R, Zimmermann Boris
Department of Biological Sciences and Bjerknes Center for Climate Research, University of Bergen, Bergen, Norway.
Norwegian University of Life Sciences, Ås, Norway.
Sci Adv. 2023 Aug 25;9(34):eadi0570. doi: 10.1126/sciadv.adi0570.
Liu present evidence of increased abundance of UV-B-absorbing compounds in fossilized sporomorphs at the end-Permian mass extinction based on Fourier transform infrared (FTIR) spectroscopy. Their approach assumes that UV-B-absorbing compounds are present in the fossilized sporomorphs spanning the extinction interval and that they can be quantified using FTIR. However, further analysis reveals that the signal that they aim to focus on is weak and poorly resolved against nonrandom background interference most likely associated with water vapor. We also show that the peak detection methods that they use are inappropriate for use on these fossil sporomorphs because their methods select only 3.9% of the spectra at the target waveband of interest. The reconstruction that they present is based on baseline variations in the spectra and cannot be confidently attributed to variations in UV-B-absorbing compounds. "Direct" evidence for UV-B radiation at the end-Permian mass extinction cannot be claimed to have been observed in this record.
刘等人基于傅里叶变换红外光谱(FTIR),展示了二叠纪末大灭绝时期化石孢子体中紫外线B吸收化合物丰度增加的证据。他们的方法假定,在跨越灭绝期的化石孢子体中存在紫外线B吸收化合物,并且可以使用FTIR对其进行量化。然而,进一步分析表明,他们旨在关注的信号较弱,并且在很可能与水蒸气相关的非随机背景干扰下分辨率较差。我们还表明,他们使用的峰值检测方法不适用于这些化石孢子体,因为他们的方法在目标感兴趣波段仅选择了3.9%的光谱。他们呈现的重建基于光谱中的基线变化,不能可靠地归因于紫外线B吸收化合物的变化。在该记录中,不能声称已观察到二叠纪末大灭绝时期紫外线B辐射的“直接”证据。