National Research Center of Intercropping, The Islamia University of Bahawalpur, Bahawalpur, Pakistan E-mail:
Institute of Soil and Environmental Sciences, PMAS-Arid Agriculture University Rawalpindi, Rawalpindi, Pakistan.
Water Sci Technol. 2023 Aug;88(4):885-900. doi: 10.2166/wst.2023.243.
A major portion of phosphatic fertilizer comes from the limiting natural resource, rock phosphate, which demands a timely alternative. Struvite, a crystalline mineral of low solubility, is a worthwhile alternative. Evaluation of the local wastewater streams for their ability to precipitate struvite and its capability as phosphatic fertilizer under an alkaline soil environment was studied. Two stirring speeds, a pH range of 8.0-11.0, and a constant molar ratio were used to optimize local wastewater streams for struvite precipitation. Struvite was used in five different combinations to assess the release of phosphorus (P), including control (no P source), single superphosphate, struvite, struvite + sulfur, and rock phosphate with or without inoculation of sulfur-oxidizing bacteria (SOB). For struvite precipitation, low stirring speeds are ideal because the precipitates readily sink to the bottom once they form. Furthermore, the amalgamation of SOB with sulfur significantly improved P use efficiency under alkaline soils through increased phosphorus sources solubility and enabled optimum wheat production due to its low solubility in an alkaline soil condition. Due to its capacity to recycle phosphorus from wastewater, struvite is poised to emerge as a sustainable fertilizer and had an opportunity to capture a share of this expanding market.
大量的磷肥来自于有限的自然资源——磷矿,这就需要一个及时的替代品。鸟粪石是一种低溶解度的结晶矿物,是一种有价值的替代品。本研究评估了当地废水在碱性土壤环境中沉淀鸟粪石的能力及其作为磷肥的能力。采用两种搅拌速度、8.0-11.0 的 pH 值范围和恒定的摩尔比,优化了当地废水的鸟粪石沉淀条件。采用五种不同的组合来评估磷(P)的释放,包括对照(无磷源)、过磷酸钙、鸟粪石、鸟粪石+硫和磷矿,或不接种硫氧化细菌(SOB)。对于鸟粪石沉淀来说,低搅拌速度是理想的,因为一旦形成沉淀,它们很容易沉降到底部。此外,SOB 与硫的结合通过增加磷源的溶解度,显著提高了碱性土壤中 P 的利用效率,并由于其在碱性土壤条件下的低溶解度,实现了最佳的小麦产量。由于鸟粪石能够从废水中回收磷,因此它有望成为一种可持续的肥料,并有可能在这个不断扩大的市场中占据一席之地。