通过内藏式铁配合物实现的协同键活化

Cooperative bond activations by a tucked-in iron complex.

作者信息

Zurakowski Joseph A, Drover Marcus W

机构信息

Department of Chemistry and Biochemistry, University of Windsor, 401 Sunset Avenue, ON, N9B 3P4, Canada.

出版信息

Chem Commun (Camb). 2023 Sep 21;59(76):11349-11352. doi: 10.1039/d3cc03325b.

DOI:10.1039/d3cc03325b

PMID:37656426

Abstract

Herein, we report the first example of a 'tucked-in' iron diphosphine complex, formed through deprotonation of a Cp*-(CH̲) (Cp* = CMe) group by -butyllithium. The reactivity of this complex was demonstrated by activation of organic and metal-containing substates, including CO, benzaldehyde, Br-Au-PPh, B(CF), and HBCy (Cy = cyclohexyl).

摘要

在此，我们报道了首例“嵌入型”二膦合铁配合物，它是通过叔丁基锂对Cp*-(CH̲)（Cp* = CMe）基团去质子化形成的。该配合物的反应活性通过活化有机和含金属底物得以证明，这些底物包括CO、苯甲醛、Br-Au-PPh、B(CF)和HBCy（Cy = 环己基）。