Santanatoglia Agnese, Alessandroni Laura, Fioretti Lauro, Sagratini Gianni, Vittori Sauro, Maggi Filippo, Caprioli Giovanni
Chemistry Interdisciplinary Project (ChIP) Research Center, School of Pharmacy, University of Camerino, Via Madonna delle Carceri 9/B, 62032 Camerino, Italy.
Research and Innovation Coffee Hub, Via Emilio Betti 1, 62020 Belforte del Chienti, Italy.
Foods. 2023 Aug 25;12(17):3199. doi: 10.3390/foods12173199.
An untargeted gas chromatography-mass spectrometry (GC-MS) approach combined with sensory analysis was used to present the effects of different extraction methods (i.e., Pure Brew, V60, AeroPress, and French Press) on specialty graded from Kenya. Partial Least Square Discriminant analysis and hierarchical clustering were applied as multivariate statistical tools in data analysis. The results showed good discrimination and a clear clustering of the groups of samples based on their volatile profiles. Similarities were found related to the filter material and shape used for the extraction. Samples extracted with paper filters (V60 and AeroPress) resulted in higher percentages of caramel-, and flowery-related compounds, while from metal filter samples (Pure Brew and French Press), more fruity and roasted coffees were obtained. Discriminant analysis allowed the identification of eight compounds with a high VIP (variable important in projection) discriminant value (i.e., >1), with 2-furanmethanol being the main feature in discrimination. Sensorial analyses were carried out through an expert panel test. The main evaluations revealed the French Press system as the lowest-scored sample in all the evaluated parameters, except for acidity, where its score was similar to V60. In conclusion, the data obtained from GC-MS analyses were in line with the sensorial results, confirming that the extraction process plays a fundamental role in the flavor profile of filter coffee beverages.
采用非靶向气相色谱 - 质谱联用(GC-MS)方法并结合感官分析,来呈现不同萃取方法(即纯酿法、V60滤杯法、爱乐压法和法式滤压壶法)对肯尼亚特色等级咖啡的影响。偏最小二乘判别分析和层次聚类被用作数据分析中的多元统计工具。结果表明,基于挥发性成分,各样本组之间具有良好的区分度和明显的聚类。发现萃取所使用的过滤材料和形状存在相似性。用纸质滤器(V60和爱乐压)萃取的样品中,焦糖和花香相关化合物的比例较高,而金属滤器样品(纯酿法和法式滤压壶)则萃取出更多果香和烘焙咖啡风味的物质。判别分析确定了8种具有高VIP(投影中变量重要性)判别值(即>1)的化合物,其中2-呋喃甲醇是区分的主要特征。通过专家小组测试进行感官分析。主要评估结果显示,除酸度外,法式滤压壶系统在所有评估参数中得分最低,其酸度得分与V60相似。总之,GC-MS分析获得的数据与感官结果一致,证实了萃取过程在过滤咖啡饮料风味特征中起着至关重要的作用。