Luo Yiqian, Mei Yixuan, Xu Yang, Huang Kun
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241, China.
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310058, China.
Nanomaterials (Basel). 2023 Sep 8;13(18):2514. doi: 10.3390/nano13182514.
Hyper-crosslinked porous organic nanomaterials, especially the hyper-crosslinked polymers (HCPs), are a unique class of materials that combine the benefits of high surface area, porous structure, and good chemical and thermal stability all rolled into one. A wide range of synthetic methods offer an enormous variety of HCPs with different pore structures and morphologies, which has allowed HCPs to be developed for gas adsorption and separations, chemical adsorption and encapsulation, and heterogeneous catalysis. Here, we present a systematic review of recent approaches to pore size modulation and morphological tailoring of HCPs and their applications to catalysis. We mainly compare the effects of pore size modulation and morphological tailoring on catalytic applications, aiming to pave the way for researchers to develop HCPs with an optimal performance for modern applications.
超交联多孔有机纳米材料，尤其是超交联聚合物（HCPs），是一类独特的材料，它将高比表面积、多孔结构以及良好的化学和热稳定性等优点集于一身。多种合成方法可制备出具有不同孔结构和形态的各种各样的HCPs，这使得HCPs能够用于气体吸附与分离、化学吸附与封装以及多相催化等领域。在此，我们对近期HCPs孔径调控和形态剪裁的方法及其在催化中的应用进行了系统综述。我们主要比较了孔径调控和形态剪裁对催化应用的影响，旨在为研究人员开发具有适用于现代应用的最佳性能的HCPs铺平道路。
