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通过添加锡增强镍铝青铜合金的微观结构和力学性能。

Enhancing microstructure and mechanical properties of nickel aluminium bronze alloy through tin addition.

作者信息

Poojary Sushanth, Marakini Vikas, Rao Rajath N, Vijayan Vijeesh

机构信息

Department of Mechanical Engineering, Nitte (Deemed to Be University), NMAM Institute of Technology (NMAMIT), Nitte, 574110, India.

出版信息

Sci Rep. 2023 Oct 7;13(1):16907. doi: 10.1038/s41598-023-44146-y.

Abstract

This article describes the changes in the microstructure, cooling curve characteristics and mechanical properties of cast Nickel Aluminium Bronze alloy (NAB) alloy that were produced by the addition of various amounts of Tin (Sn). The solidification parameters were recorded using a computer-aided cooling curve analysis setup, and optical and scanning electron microscopes were utilised to study the evolution of the microstructure. The chemical composition of different phases generated in the NAB alloy with and without Tin was investigated using an X-ray diffraction technique. With the addition of tin, the alloy's microstructure changed from columnar to equiaxed grain structures, and the ideal microstructure was produced at a Tin concentration of roughly 1.0 weight percent. The formation of the high temperature α and the grain boundary Sn rich phases across the alloy microstructure as a result of further addition has a considerable impact on the alloy's increased hardness (upto 69%) and tensile strength (upto 28.4%) compared to untreated NAB alloy. Influence of Sn on microstructure transformation is confirmed by the decline in alloy nucleation temperatures, the reduction in undercooling intensity, and the decrease in cooling rate during solidification. The addition of Tin to the NAB alloy caused morphological changes in the kappa (K) phases, which are also reported in the this article. In addition to this, the research makes an attempt to describe the mechanism underlying the formation of equiaxed grains and phase transformations in Sn-treated NAB alloys.

摘要

本文描述了通过添加不同量的锡(Sn)所生产的铸造镍铝青铜合金(NAB)的微观结构、冷却曲线特征和力学性能的变化。使用计算机辅助冷却曲线分析装置记录凝固参数,并利用光学显微镜和扫描电子显微镜研究微观结构的演变。采用X射线衍射技术研究了添加锡和未添加锡的NAB合金中生成的不同相的化学成分。随着锡的添加,合金的微观结构从柱状晶粒结构转变为等轴晶粒结构,在锡浓度约为1.0重量百分比时产生了理想的微观结构。与未处理的NAB合金相比,进一步添加锡导致合金微观结构中高温α相和富锡晶界相的形成,对合金硬度(高达69%)和抗拉强度(高达28.4%)的增加有相当大的影响。合金形核温度的下降、过冷强度的降低以及凝固过程中冷却速率的降低证实了锡对微观结构转变的影响。向NAB合金中添加锡导致κ(K)相的形态发生变化,本文也对此进行了报道。除此之外,该研究还试图描述经锡处理的NAB合金中等轴晶粒形成和相变的潜在机制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/59e4/10560272/f4cf1f711b1f/41598_2023_44146_Fig1_HTML.jpg

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