Lamb Angela L, Chenery Carolyn A, Madgwick Richard, Evans Jane A
National Environmental Isotope Facility, British Geological Survey, Keyworth, Nottingham NG12 5GG, UK.
School of History, Archaeology and Religion, Cardiff University, Cardiff CF10 3EU, UK.
R Soc Open Sci. 2023 Oct 11;10(10):230391. doi: 10.1098/rsos.230391. eCollection 2023 Oct.
The stable isotopes of sulfur provide a distinctive signature for marine proximity and interaction. Exploring coastal proximity has been the principal application of sulfur isotopes in archaeology and palaeoecology, but this deals only with high (greater than 14‰) isotope values, meaning little interpretation has been gained from lower values. Progress has been hindered by issues with biosphere mapping. Air pollution can impact modern landscapes, significantly lowering sulfur isotope baselines, leading to the assumption that modern vegetation-based sulfur maps are not reliable. This research explores the potential of previously undiagnostic low, and often, negative sulfur isotope values for identifying wetland dwellers. Impervious clays that support wetlands are distinctive ecosystems and this study tests the hypothesis that they will produce low isotope values owing to both the underlying substrate and to redox conditions. Primary mapping of targeted areas using modern plants highlights zones with natural negative sulfur values and demonstrates that this constitutes a distinctive wetland signature. Analysis of modern and archaeological fauna demonstrates that these distinctive isotope compositions are transferred into the food chain. These findings propel the interpretative potential of sulfur isotopes forward and add to the growing knowledge to provide means for identifying archaeological humans and animals raised in wetlands.
硫的稳定同位素为海洋的接近程度和相互作用提供了独特的特征。探索与海岸的接近程度一直是硫同位素在考古学和古生态学中的主要应用,但这仅涉及高(大于14‰)同位素值,这意味着从较低值中获得的解释很少。生物圈测绘问题阻碍了进展。空气污染会影响现代景观,显著降低硫同位素基线,导致人们认为基于现代植被的硫地图不可靠。本研究探索了以前无法诊断的低硫同位素值(通常为负)在识别湿地居民方面的潜力。支撑湿地的不透水粘土是独特的生态系统,本研究检验了这样一个假设,即由于底层基质和氧化还原条件,它们会产生低同位素值。利用现代植物对目标区域进行初步测绘,突出了具有天然负硫值的区域,并表明这构成了独特的湿地特征。对现代和考古动物群的分析表明,这些独特的同位素组成会转移到食物链中。这些发现推动了硫同位素的解释潜力,并增加了日益增长的知识,为识别在湿地中饲养的考古人类和动物提供了方法。