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用于高性能和防雨摩擦纳米发电机的电荷分散策略

Charge Dispersion Strategy for High-Performance and Rain-Proof Triboelectric Nanogenerator.

作者信息

Sun Qizeng, Ren Guozhang, He Shunhao, Tang Biao, Li Yijia, Wei Yuewen, Shi Xuewen, Tan Shenxing, Yan Ren, Wang Kaili, Yu Liuyingzi, Wang Junjie, Gao Kun, Zhu Chengcheng, Song Yaxin, Gong Zhongyan, Lu Gang, Huang Wei, Yu Hai-Dong

机构信息

Frontiers Science Center for Flexible Electronics, Xi'an Institute of Flexible Electronics, Xi'an Institute of Biomedical Materials & Engineering, Northwestern Polytechnical University, 127 West Youyi Road, Xi'an, 710072, P. R. China.

School of Flexible Electronics (Future Technologies), Institute of Advanced Materials, Key Laboratory of Flexible Electronics, Nanjing Tech University, 30 South Puzhu Road, Nanjing, 211816, P. R. China.

出版信息

Adv Mater. 2024 Feb;36(8):e2307918. doi: 10.1002/adma.202307918. Epub 2023 Nov 30.

DOI:10.1002/adma.202307918
PMID:37852010
Abstract

Triboelectric nanogenerator (TENG) is becoming a sustainable and renewable way of energy harvesting and self-powered sensing because of low cost, simple structure, and high efficiency. However, the output current of existing TENGs is still low. It is proposed that the output current of TENGs can be dramatically improved if the triboelectric charges can distribute inside the triboelectric layers. Herein, a novel single-electrode conductive network-based TENG (CN-TENG) is developed by introducing a conductive network of multiwalled carbon nanotubes in dielectric triboelectric layer of thermoplastic polyurethane (TPU). In this CN-TENG, the contact electrification-induced charges distribute on both the surface and interior of the dielectric TPU layer. Thus, the short-circuit current of CN-TENG improves for 100-fold, compared with that of traditional dielectric TENG. In addition, this CN-TENG, even without packing, can work stably in high-humidity environments and even in the rain, which is another main challenge for conventional TENGs due to charge leakage. Further, this CN-TENG is applied for the first time, to successfully distinguish conductive and dielectric materials. This work provides a new and effective strategy to fabricate TENGs with high output current and humidity-resistivity, greatly expanding their practical applications in energy harvesting, movement sensing, human-machine interaction, and so on.

摘要

摩擦纳米发电机(TENG)因其成本低、结构简单和效率高,正成为一种可持续和可再生的能量收集及自供电传感方式。然而,现有TENG的输出电流仍然较低。有人提出,如果摩擦电荷能够在摩擦电层内部分布,TENG的输出电流可以显著提高。在此,通过在热塑性聚氨酯(TPU)的介电摩擦电层中引入多壁碳纳米管导电网络,开发了一种新型的基于单电极导电网络的TENG(CN-TENG)。在这种CN-TENG中,接触起电产生的电荷分布在介电TPU层的表面和内部。因此,与传统介电TENG相比,CN-TENG的短路电流提高了100倍。此外,这种CN-TENG即使不封装,也能在高湿度环境甚至雨中稳定工作,而电荷泄漏是传统TENG面临的另一个主要挑战。此外,这种CN-TENG首次被应用于成功区分导电材料和介电材料。这项工作为制造具有高输出电流和耐湿性的TENG提供了一种新的有效策略,极大地扩展了它们在能量收集、运动传感、人机交互等方面的实际应用。

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引用本文的文献

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A review of material design for high performance triboelectric nanogenerators: performance improvement based on charge generation and charge loss.高性能摩擦纳米发电机的材料设计综述:基于电荷产生和电荷损失的性能提升
Nanoscale Adv. 2024 Jul 24;6(18):4522-4544. doi: 10.1039/d4na00340c. eCollection 2024 Sep 10.