动脉内（神经组织因子）：动脉内氧化能力的边界？
ArI(NTf): the boundary of oxidative capacity for ArIL?
作者信息
Barwise Lachlan, Bennetts Jason D, White Keith F, Dutton Jason L
机构信息
Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia.
出版信息
Chem Commun (Camb). 2023 Nov 7;59(89):13340-13343. doi: 10.1039/d3cc04563c.
Synthesis and crystallographic characterization of NO-CH-I(NTf) (NTf = bistriflimide) is reported. Experimental results find that this compound can perform oxidation reactions that ArI(OTf) is unable to and theoretical analysis indicates Ar-I(NTf) is the most oxidizing in the ArIL class of compounds known and may also be the most oxidizing compound in the class practically possible.
报道了NO-CH-I(NTf)（NTf = 双三氟甲磺酰亚胺）的合成及晶体学表征。实验结果发现，该化合物能够进行ArI(OTf)无法进行的氧化反应，理论分析表明，Ar-I(NTf)是已知的ArIL类化合物中氧化性最强的，也可能是实际可能的此类化合物中氧化性最强的。
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