Ding Lijie, Pelcovits Robert A, Powers Thomas R
Department of Physics, Brown University, Providence, RI 02912, USA.
Brown Theoretical Physics Center, Brown University, Providence, RI 02912, USA.
Soft Matter. 2023 Nov 8;19(43):8453-8464. doi: 10.1039/d3sm01158e.
We carry out Monte Carlo simulations on fluid membranes with orientational order and multiple edges in the presence and absence of external forces. The membrane resists bending and has an edge tension, the orientational order couples with the membrane surface normal through a cost for tilting, and there is a chiral liquid crystalline interaction. In the absence of external forces, a membrane initialized as a vesicle will form a disk at low chirality, with the directors forming a smectic-A phase with alignment perpendicular to the membrane surface except near the edge. At large chirality a catenoid-like shape or a trinoid-like shape is formed, depending on the number of edges in the initial vesicle. This shape change is accompanied by cholesteric ordering of the directors and multiple π walls connecting the membrane edges and wrapping around the membrane neck. If the membrane is initialized instead in a cylindrical shape and stretched by an external force, it maintains a nearly cylindrical shape but additional liquid crystalline phases appear. For large tilt coupling and low chirality, a smectic-A phase forms where the directors are normal to the surface of the membrane. For lower values of the tilt coupling, a nematic phase appears at zero chirality with the average director oriented perpendicular to the long axis of the membrane, while for nonzero chirality a cholesteric phase appears. The π walls are tilt walls at low chirality and transition to twist walls as chirality is increased. We construct a continuum model of the director field to explain this behavior.
我们在存在和不存在外力的情况下,对具有取向有序和多条边缘的流体膜进行蒙特卡罗模拟。膜具有抗弯曲能力和边缘张力,取向有序通过倾斜成本与膜表面法线耦合,并且存在手性液晶相互作用。在没有外力的情况下,初始化为囊泡的膜在低手性时会形成圆盘,除了在边缘附近,指向矢形成垂直于膜表面排列的近晶 - A相。在大手性时,会形成类链状或类三叶状形状,这取决于初始囊泡中的边缘数量。这种形状变化伴随着指向矢的胆甾相有序排列以及连接膜边缘并环绕膜颈部的多个π壁。如果膜改为初始化为圆柱形并受到外力拉伸,它会保持近乎圆柱形的形状,但会出现额外的液晶相。对于大的倾斜耦合和低手性,会形成指向矢垂直于膜表面的近晶 - A相。对于较低的倾斜耦合值,在手性为零时会出现向列相,平均指向矢垂直于膜的长轴,而在非零手性时会出现胆甾相。π壁在低手性时是倾斜壁,随着手性增加会转变为扭曲壁。我们构建了指向矢场的连续介质模型来解释这种行为。