Department of Chemical Engineering, Sri Venkateswara College of Engineering, Chennai, Tamil Nadu, 602117, India.
Department of Chemical Engineering, Indian Institute of Technology Madras, Chennai, Tamil Nadu, 600036, India.
Environ Res. 2024 Jan 1;240(Pt 2):117500. doi: 10.1016/j.envres.2023.117500. Epub 2023 Oct 31.
The existence of various pollutants in water environment contributes to global pollution and poses significant threats to humans, wildlife, and other living beings. The emergence of an effective, realistic, cost-effective, and environmentally acceptable technique to treat wastewater generated from different sectors is critical for reducing pollutant accumulation in the environment. The electrochemical advanced oxidation method is a productive technology for treating hazardous effluents because of its potential benefits such as lack of secondary pollutant and high oxidation efficiency. Recent researches on advanced oxidation processes (AOPs) in the period of 2018-2022 are highlighted in this paper. This review emphasizes on recent advances in electro-oxidation (EO), ozone oxidation, sonolysis, radiation, electro-Fenton (EF), photolysis and photocatalysis targeted at treating pharmaceuticals, dyes and pesticides polluted effluents. In the first half of the review, the concept of the AOPs are discussed briefly. Later, the influence of increasing current density, pH, electrode, electrolyte and initial concentration of effluents on degradation are discussed. Lastly, previously reported designs of electrochemical reactors, as well as data on intermediates generated and energy consumption during the electro oxidation and Fenton processes are discussed. According to the literature study, the electro-oxidation technique is more appropriate for organic compounds, whilst the electro-Fenton technique appear to be more appropriate for more complex molecules.
水环境中各种污染物的存在导致了全球污染,并对人类、野生动物和其他生物构成了重大威胁。因此,开发一种有效、现实、具有成本效益且环境可接受的技术来处理来自不同领域的废水,对于减少环境中污染物的积累至关重要。电化学高级氧化法是一种处理危险废水的有前途的技术,因为它具有无二次污染物和高氧化效率等潜在优势。本文重点介绍了 2018 年至 2022 年期间高级氧化工艺(AOPs)的最新研究进展。本综述强调了最近在电氧化(EO)、臭氧氧化、超声降解、辐射、电芬顿(EF)、光解和光催化方面的进展,这些方法针对处理受药物、染料和农药污染的废水。在综述的前半部分,简要讨论了 AOPs 的概念。随后,讨论了电流密度、pH 值、电极、电解质和废水初始浓度对降解的影响。最后,讨论了电化学反应器的先前报道设计以及电氧化和芬顿过程中生成的中间体和能耗的数据。根据文献研究,电氧化技术更适合处理有机化合物,而电芬顿技术似乎更适合处理更复杂的分子。