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不同浓度的天然染料降胭脂树素钾(胭脂树提取物)在聚酰胺6.6织物中的应用。

Application of different concentrations of the natural dye potassium norbixinate (annatto) in polyamide 6.6 fabrics.

作者信息

Gonçalves Marcel Jefferson, de Oliveira Ariane Canuto Veiga, Colla Prando Amábile, Krebs de Souza Carolina, Siqueira Curto Valle Rita de Cassia, Barcellos Ivonete Oliveira, Tavares Lorena Benathar Ballod

机构信息

Postgraduate Program in Environmental Engineering, Regional University of Blumenau (FURB), Blumenau, Brazil.

Chemical Engineering Department, Regional University of Blumenau (FURB), Blumenau, Brazil.

出版信息

Nat Prod Res. 2025 Apr;39(7):1856-1863. doi: 10.1080/14786419.2023.2280178. Epub 2023 Nov 11.

Abstract

Polyamide fabrics were dyed with concentrations ranging from 4% to 0.25% (o.w.f.) of the natural dye, potassium norbixinate (annatto). The exhaustion, chromatic coordinates, colouristic intensity (K/S), and fastness to washing and rubbing were evaluated. The natural dye was characterised, and its maximum absorption peaks were identified at 452 nm and 482 nm through UV-vis scanning. Its main chemical groups were identified by FTIR-ATR. All dyeings exhibited high exhaustion percentage, with a maximum of 98.4% for 1% dye concentration. The dyed samples displayed visually appealing orange hues, with a maximum K/S value of 6.9. Most of the fastness test results were rated between 5 and 4/5, remaining within the standards established by most textile industries. Potassium norbixinate exhibited a similar tinctorial behaviour to synthetic acid dyes for polyamide, suggesting ionic chemical reaction interaction between dye and polyamide, highlighting the potential use in the textile industry.

摘要

采用浓度范围为4%至0.25%(对织物重量)的天然染料降胭脂树素钾(胭脂树橙)对聚酰胺织物进行染色。对其竭染率、色度坐标、色强度(K/S)以及耐洗和耐摩擦牢度进行了评估。对该天然染料进行了表征,并通过紫外可见扫描确定其在452nm和482nm处有最大吸收峰。通过傅里叶变换红外光谱-衰减全反射法(FTIR-ATR)确定了其主要化学基团。所有染色的竭染率都很高,染料浓度为1%时最高可达98.4%。染色后的样品呈现出视觉上吸引人的橙色,最大K/S值为6.9。大多数牢度测试结果评级在4/5至5之间,符合大多数纺织行业制定的标准。降胭脂树素钾对聚酰胺的染色行为与合成酸性染料相似,表明染料与聚酰胺之间存在离子化学反应相互作用,突出了其在纺织工业中的潜在用途。

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