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周期性博罗梅安环、杆和链。

Periodic Borromean rings, rods and chains.

作者信息

O'Keeffe Michael, Treacy Michael M J

机构信息

School of Molecular Sciences, Arizona State University, Tempe, AZ 85287, USA.

Department of Physics, Arizona State University, Tempe, AZ 85287, USA.

出版信息

Acta Crystallogr A Found Adv. 2024 Jan 1;80(Pt 1):79-85. doi: 10.1107/S2053273323009269.

Abstract

This article describes periodic polycatenane structures built from interlocked rings in which no two are directly linked. The 2-periodic vertex-, edge- and ring-transitive families of hexagonal Borromean rings are described in detail, and it is shown how these give rise to 1- and 3-periodic ring-transitive (isonemal) families. A second isonemal 2-periodic family is identified, as is a unique 3-periodic Borromean assembly of equilateral triangles. Also reported is a notable 2-periodic structure comprising chains of linked rings in which the chains are locked in place but no two chains are directly interlinked, being held in place as a novel `quasi-Borromean' set of four repeating components.

摘要

本文描述了由互锁环构建的周期性多链烷结构,其中没有两个环直接相连。详细描述了六边形博罗梅安环的2周期顶点传递、边传递和环传递族,并展示了这些族如何产生1周期和3周期的环传递(等轴)族。确定了第二个等轴2周期族,以及一个独特的等边三角形3周期博罗梅安组合。还报道了一种显著的2周期结构,它由相连环的链组成,其中链被锁定在适当位置,但没有两条链直接相互连接,而是作为一组由四个重复组件组成的新型“准博罗梅安”结构固定在适当位置。

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