Vaičiukynienė Danutė, Nizevičienė Dalia, Kantautas Aras, Tamošaitis Gintautas, Fornés Ignacio Villalón, Krivenko Pavel, Boiko Olha
Building Materials and Structures Research Centre, Faculty of Civil Engineering and Architecture, Kaunas University of Technology, Studentu st. 48, 51367, Kaunas, Lithuania.
Department of Electrical Power Systems, Faculty of Electrical and Electronics Engineering, Kaunas University of Technology, Studentu st. 48, 51367, Kaunas, Lithuania.
Sci Rep. 2024 Jan 2;14(1):188. doi: 10.1038/s41598-023-50761-6.
The production of ordinary Portland cement (OPC) is one of the main global causes of CO release to the atmosphere. However, its availability and unique characteristics as a binding material make it difficult to be substituted by eco-friendlier materials. However, OPC partial replacement with pozzolanic materials is one of the best solutions to this problem. Hence, in this study, various types of high-volume zeolite were employed as supplementary cementitious materials (SCM), substituting the OPC by up to 50 wt.% in the composition of the created mortars. Besides, quicklime and inorganic accelerators were included in some of the mortar mixtures to improve the hydration reaction and enhance its speed. The mechanical, durability and durability in sea water properties were investigated. Although the usage of SCM caused a decrease in the mechanical and durability properties of the specimens, the addition of 10 wt.% quicklime palliated this degradation by enhancing by 40% the 28-days compressive strength of the specimens and by significantly improving their durability (porosity, freeze-thaw resistance and carbonation resistance). Moreover, the mixtures were proved to be resistance to aggressive ionic environments, since their compressive strength even increased after 28-day immersion in seawater, due to the additional formation of hydration compounds.
普通硅酸盐水泥(OPC)的生产是全球大气中二氧化碳排放的主要原因之一。然而,其作为胶凝材料的可用性和独特特性使其难以被更环保的材料替代。不过,用火山灰质材料部分替代OPC是解决这一问题的最佳方案之一。因此,在本研究中,使用了各种类型的高掺量沸石作为辅助胶凝材料(SCM),在制成的砂浆成分中替代高达50 wt.%的OPC。此外,一些砂浆混合物中还加入了生石灰和无机促进剂,以改善水化反应并提高其速度。对其力学性能、耐久性以及在海水中的耐久性进行了研究。虽然使用SCM导致试件的力学性能和耐久性下降,但添加10 wt.%的生石灰缓解了这种劣化,使试件的28天抗压强度提高了40%,并显著改善了其耐久性(孔隙率、抗冻融性和抗碳化性)。此外,这些混合物被证明对侵蚀性离子环境具有抗性,因为在海水中浸泡28天后,由于水化产物的额外形成,其抗压强度甚至有所提高。