Clarke Alison J, Dickson Andrew, Dowling Denis P
I-Form Centre, School of Mechanical & Materials Engineering, University College Dublin, Belfield, D04 C1P1 Dublin, Ireland.
Infraprint, Nova UCD, Belfield, D04 C1P1 Dublin, Ireland.
Polymers (Basel). 2023 Dec 24;16(1):63. doi: 10.3390/polym16010063.
This study investigates the feasibility of 3D printing continuous stainless steel fibre-reinforced polymer composites. The printing study was carried out using 316L stainless steel fibre (SSF) bundles with an approximate diameter of 0.15 mm. This bundle was composed of 90 fibres with a 14 μm diameter. This fibre bundle was first coated with polylactic acid (PLA) in order to produce a polymer-coated continuous stainless steel filament, with diameters tailored in the range from 0.5 to 0.9 mm. These filaments were then used to print composite parts using the material extrusion (MEX) technique. The SSF's volume fraction (Vf) was controlled in the printed composite structures in the range from 4 to 30 Vf%. This was facilitated by incorporating a novel polymer pressure vent into the printer nozzle, which allowed the removal of excess polymer. This thus enabled the control of the metal fibre content within the printed composites as the print layer height was varied in the range from 0.22 to 0.48 mm. It was demonstrated that a lower layer height yielded a more homogeneous distribution of steel fibres within the PLA polymer matrix. The PLA-SSF composites were assessed to evaluate their mechanical performance, volume fraction, morphology and porosity. Composite porosities in the range of 2-21% were obtained. Mechanical testing demonstrated that the stainless steel composites exhibited a twofold increase in interlaminar shear strength (ILSS) and a fourfold increase in its tensile strength compared with the PLA-only polymer prints. When comparing the 4 and 30 Vf% composites, the latter exhibited a significant increase in both the tensile strength and modulus. The ILSS values obtained for the steel composites were up to 28.5 MPa, which is significantly higher than the approximately 13.8 MPa reported for glass fibre-reinforced PLA composites.
本研究调查了3D打印连续不锈钢纤维增强聚合物复合材料的可行性。打印研究使用了直径约为0.15毫米的316L不锈钢纤维(SSF)束进行。该纤维束由90根直径为14微米的纤维组成。该纤维束首先用聚乳酸(PLA)进行涂层,以生产直径定制在0.5至0.9毫米范围内的聚合物涂层连续不锈钢长丝。然后使用这些长丝通过材料挤出(MEX)技术打印复合部件。在打印的复合结构中,SSF的体积分数(Vf)控制在4至30 Vf%的范围内。这通过在打印机喷嘴中加入一种新型聚合物压力通风口得以实现,该通风口可去除多余的聚合物。因此,随着打印层高度在0.22至0.48毫米范围内变化,能够控制打印复合材料中的金属纤维含量。结果表明,较低的层高度在PLA聚合物基体中产生了更均匀的钢纤维分布。对PLA-SSF复合材料进行了评估,以评价其机械性能、体积分数、形态和孔隙率。获得了2-21%范围内的复合孔隙率。机械测试表明,与仅PLA聚合物打印件相比,不锈钢复合材料的层间剪切强度(ILSS)提高了两倍,拉伸强度提高了四倍。当比较4 Vf%和30 Vf%的复合材料时,后者的拉伸强度和模量均显著提高。钢复合材料获得的ILSS值高达28.5 MPa,明显高于玻璃纤维增强PLA复合材料报道的约13.8 MPa。