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用于聚合物光纤技术的在两种不同沸点溶剂中合成CdSe量子点

Synthesis of CdSe Quantum Dots in Two Solvents of Different Boiling Points for Polymer Optical Fiber Technology.

作者信息

Kiczor Anna, Mergo Paweł

机构信息

Laboratory of Optical Fibers Technology, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Skłodowska University in Lublin, M. Curie-Skłodowska Sq.5, 20-031 Lublin, Poland.

出版信息

Materials (Basel). 2023 Dec 31;17(1):227. doi: 10.3390/ma17010227.

Abstract

Polymer materials find many applications in various industries. Efforts are being made to obtain structures with increasingly better properties. It is necessary not only to obtain new materials but also to modify existing structures. Such is the situation with polymer optical fibers. The widespread use of polymer optical fibers is impossible, due to their very high optical losses compared to glass optical fibers. The solution to this problem can be the manufacturing of polymer active optical fibers. Active fibers are the basic components of fiber optic amplifiers and lasers that allow the direct amplification of light inside the fiber. In order for their operation to be the most effective, it is necessary to use dopants. The most commonly used are lanthanide ions isolated from the polymer network, active organic dyes, and quantum dots. These dopants are characterized by very high luminescence and long glow times. Quantum dots of CdSe are made using two organic solvents that differ in boiling points-hexane (a low-boiling solvent with a boiling point of 69 °C) and 1-octadecene (a high-boiling solvent with a boiling point of 315 °C). This work aims to test whether the type of solvent used to obtain quantum dots affects the doping capabilities of polymer structures, from which optical fibers can then be drawn.

摘要

聚合物材料在各个行业有许多应用。人们正在努力获得性能越来越好的结构。不仅需要获得新材料,还需要对现有结构进行改性。聚合物光纤就是这种情况。由于与玻璃光纤相比,聚合物光纤的光损耗非常高,因此其广泛应用是不可能的。解决这个问题的方法可以是制造聚合物有源光纤。有源光纤是光纤放大器和激光器的基本组件,可在光纤内部直接放大光。为了使其运行最有效,有必要使用掺杂剂。最常用的是从聚合物网络中分离出来的镧系离子、活性有机染料和量子点。这些掺杂剂具有非常高的发光率和较长的发光时间。CdSe量子点是使用两种沸点不同的有机溶剂制成的——己烷(沸点为69°C的低沸点溶剂)和1-十八烯(沸点为315°C的高沸点溶剂)。这项工作旨在测试用于获得量子点的溶剂类型是否会影响聚合物结构的掺杂能力,然后可以从中拉制出光纤。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8989/10779661/12f8cb43f2dc/materials-17-00227-g001.jpg

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