Detzel Martin, Mitschang Peter, Breuer Ulf
Leibniz-Institut fuer Verbundwerkstoffe GmbH, Erwin-Schroedinger-Strasse 58, 67663 Kaiserslautern, Germany.
Polymers (Basel). 2023 Nov 30;15(23):4575. doi: 10.3390/polym15234575.
This study describes a novel process in which staple fiber yarns made from recycled carbon fibers (rCFs) and polyamide 6 (PA6) fibers are further processed into semi-finished tape products in a modified impregnation and calendaring process. In this process, the staple fiber yarns are heated above the melting temperature of the polymer, impregnated, and stretched to staple fiber tapes (SF tapes) in the calendaring unit. SF tapes with different degrees of stretching and/or repasses were produced. The individual width and thickness were measured in line by a laser profile sensor. From these tapes, preforms were manually laid and processed into laminates in an autoclave. The important physical properties of the unidirectionally reinforced laminates made of the tapes were compared with organic sheets wound from staple fiber yarns. With increasing stretching, both the fiber orientation and mechanical properties improved compared to the organic sheets made from unstretched staple fiber yarns. An improvement in fiber orientation relative to the process direction from 66.3% to 91.9% (between ±10°) and 39.1% to 71.6% (between ±5°), respectively, was achieved for a two-stage stretched tape. The tensile and flexural moduli were increased by 15.2% and 14.5%, respectively.
本研究描述了一种新工艺,其中由回收碳纤维(rCF)和聚酰胺6(PA6)纤维制成的短纤维纱线通过改良的浸渍和压延工艺进一步加工成半成品带材产品。在该工艺中,短纤维纱线被加热至聚合物的熔点以上,进行浸渍,并在压延单元中拉伸成短纤维带(SF带)。制备了具有不同拉伸程度和/或再通过次数的SF带。通过激光轮廓传感器在线测量其各自的宽度和厚度。从这些带材中,手工铺设预成型件并在高压釜中加工成层压板。将由这些带材制成的单向增强层压板的重要物理性能与由短纤维纱线缠绕而成的有机片材进行了比较。与由未拉伸短纤维纱线制成的有机片材相比,随着拉伸程度的增加,纤维取向和机械性能均得到改善。对于两阶段拉伸带材,相对于加工方向的纤维取向分别从66.3%提高到91.9%(±10°之间)和从39.1%提高到71.6%(±5°之间)。拉伸模量和弯曲模量分别提高了15.2%和14.5%。