5-溴取代嘧啶核苷与碱水溶液的反应：动力学与机理
Reactions of 5-bromo substituted pyrimidine nucleosides with aqueous alkalies: kinetics and mechanisms.
作者信息
Käppi R, Lönnberg H
出版信息
Acta Chem Scand B. 1986 Oct;40(9):768-75. doi: 10.3891/acta.chem.scand.40b-0768.
Abstract
Kinetics for the parallel and consecutive steps of the reactions of 5-bromocytidine, 5-bromouridine and its 5'-O-methyl and 2',3'-O-isopropylidene derivatives with aqueous alkalies were studied by LC. The mechanisms of the partial reactions involved are discussed.
摘要
采用液相色谱法研究了5-溴胞苷、5-溴尿苷及其5'-O-甲基和2',3'-O-亚异丙基衍生物与碱水溶液反应的平行和连续步骤的动力学。讨论了所涉及的部分反应的机理。
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