双[2,6-双（苯并咪唑-2-基）吡啶-κ,','']镍（II）双（三氟甲磺酸）二乙醚单溶剂合物
Bis[2,6-bis-(benzimidazol-2-yl)pyridine-κ,','']nickel(II) bis-(tri-fluoro-methane-sulfonate) diethyl ether monosolvate.
作者信息
Ruiz Sarah E, Arman Hadi D, Adrian Rafael A
机构信息
Department of Chemistry and Biochemistry, University of the Incarnate Word, San Antonio, Texas 78209, USA.
Department of Chemistry, The University of Texas at San Antonio, San Antonio, Texas 78249, USA.
出版信息
IUCrdata. 2024 Jan 31;9(Pt 1):x240088. doi: 10.1107/S2414314624000889. eCollection 2024 Jan.
In the title complex, Ni(CHN)·(CHCH)O, the central Ni atom is sixfold coordinated by three nitro-gen atoms of each 2,6-bis-(2-benzimidazol-yl)pyridine ligand in a distorted octa-hedral geometry with two tri-fluoro-methane-sulfonate ions and a mol-ecule of diethyl ether completing the outer coordination sphere of the complex. Hydrogen bonding contributes to the organization of the asymmetric units in columns along the axis generating a porous supra-molecular structure. The structure was refined as a two-component twin with a refined BASF value of 0.4104 (13).
在标题配合物Ni(CHN)·(CHCH)O中，中心Ni原子由每个2,6-双（2-苯并咪唑基）吡啶配体的三个氮原子以扭曲的八面体几何构型六配位，两个三氟甲磺酸根离子和一个二乙醚分子构成配合物的外配位层。氢键作用有助于不对称单元沿轴排列成列，从而产生多孔超分子结构。该结构作为双组分孪晶进行精修，精修的BASF值为0.4104 (13)。
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