Lin Zhuoling, Zhang Yaduo, Liang Xiaoliang, Huang Guangqing, Fan Fenglei, Yin Xiaoling, Chen Zhihao
Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, 510640, PR China; Guangdong Public Laboratory of Geospatial Information Technology and Application, Guangzhou Institute of Geography, Guangdong Academy of Sciences Guangzhou, 510070, PR China; University of Chinese Academy of Sciences, Beijing, 100049, PR China.
School of Geography, South China Normal University, Guangzhou, 510631, PR China.
Chemosphere. 2024 Mar;352:141374. doi: 10.1016/j.chemosphere.2024.141374. Epub 2024 Feb 9.
Despite the widespread occurrence of regolith-hosted rare earth elements (REEs) across South China, their spatial distribution characteristics in soils and their impact factors remain largely uncertain. This knowledge gap impedes the exploration of regolith-hosted REE deposits and the assessment of the environmental risks associated with REEs. To address this issue, 180 soil samples were collected from Meizhou City, Guangdong Province, a region known for its high abundance of regolith-hosted REEs. Subsequently, the correlations between REE enrichment/fractionation and various factors, i.e., topography, climate conditions, land use, and landform were analysed using the geo-detector method. The results revealed a highly uneven spatial distribution of REEs and their fractionation features with some regions displaying distinct spatial patterns. Elevation was the dominant factor influencing this distribution, and showed strong correlations with the concentrations of REEs, light REEs (LREEs) and heavy REEs (HREEs); the LREE/HREE ratio; and the positive Ce anomaly (δCe). The negative Eu anomaly (δEu) showed a good correlation with rock type. The enrichment and fractionation of REEs indicated a coupling among the abovementioned factors. For REE enrichment, areas with elevations of 138-148 m, precipitation levels of 1553-1574 mm, annual average land surface temperatures of 30.4-30.5 °C, leaf area index values of 22-29 and surface cutting degree of 21.5-29.9 m showed the highest average abundance within each type (scope) of the predominant factors. These findings highlight the key factors affecting REE distribution, thereby aiding the efficient utilization of regolith-hosted REE resources and the evaluation of their environmental risks.
尽管风化壳型稀土元素(REEs)在华南地区广泛分布,但其在土壤中的空间分布特征及其影响因素仍存在很大不确定性。这一知识空白阻碍了风化壳型稀土矿床的勘探以及与稀土元素相关的环境风险评估。为解决这一问题,从广东省梅州市采集了180个土壤样本,该地区以风化壳型稀土元素含量高而闻名。随后,采用地理探测器方法分析了稀土元素富集/分馏与各种因素之间的相关性,即地形、气候条件、土地利用和地貌。结果表明,稀土元素的空间分布极不均匀,且具有分馏特征,部分区域呈现出明显的空间格局。海拔是影响这种分布的主导因素,与稀土元素、轻稀土元素(LREEs)和重稀土元素(HREEs)的浓度;LREE/HREE比值;以及正铈异常(δCe)均呈强相关。负铕异常(δEu)与岩石类型呈现出良好的相关性。稀土元素的富集和分馏表明上述因素之间存在耦合关系。对于稀土元素富集而言,海拔在138 - 148米、降水量在1553 - 1574毫米、年平均地表温度在30.4 - 30.5℃、叶面积指数值在22 - 29以及地表切割度在21.5 - 29.9米的区域,在各主要因素的每种类型(范围)内显示出最高的平均丰度。这些发现突出了影响稀土元素分布的关键因素,从而有助于风化壳型稀土资源的高效利用及其环境风险评估。