钯催化1,n-二烯不对称Heck/Tsuji-Trost反应的最新进展
Recent Advances in Palladium-Catalyzed Asymmetric Heck/Tsuji-Trost Reactions of 1,n-Dienes.
作者信息
Zhao Guofeng, Li Wenbo, Zhang Junliang
机构信息
School of Chemistry and Chemical Engineering, Henan University of Science and Technology, Luoyang, 471023, China.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, State Key Laboratory of Petroleum Molecular & Process Engineering, School of Chemistry and Molecular Engineering, East China Normal University, 3663 N. Zhongshan Road, Shanghai, 200062, P. R. China.
出版信息
Chemistry. 2024 May 8;30(26):e202400076. doi: 10.1002/chem.202400076. Epub 2024 Feb 29.
Transition-metal catalyzed tandem asymmetric reactions were powerful tools to access various chiral compounds. Many strategies have been developed for the coupling of 1,n-dienes with aryl halides via a tandem Heck/Tsuji-Trost process. However, the control of regio- and stereo-chemistry remains a challenging task. This minireview details the recent advances in the field of asymmetric Heck/Tsuji-Trost reactions catalyzed by palladium complex, which have opened new opportunities and expanded our understanding in this area of research in recent years.
过渡金属催化的串联不对称反应是获得各种手性化合物的有力工具。通过串联Heck/Tsuji-Trost过程，已开发出许多用于1,n-二烯与芳基卤化物偶联的策略。然而，区域化学和立体化学的控制仍然是一项具有挑战性的任务。这篇综述详细介绍了钯配合物催化的不对称Heck/Tsuji-Trost反应领域的最新进展，这些进展近年来为该研究领域带来了新的机遇并拓展了我们的认识。
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