澳大利亚昆士兰州东南部莫顿湾沉积物中的塑料污染。

Plastic pollution in Moreton Bay sediments, Southeast Queensland, Australia.

作者信息

Okoffo Elvis D, Tan Emmeline, Grinham Alistair, Gaddam Sai Meghna Reddy, Yip Josie Yee Hang, Twomey Alice J, Thomas Kevin V, Bostock Helen

机构信息

Queensland Alliance for Environmental Health Sciences (QAEHS), The University of Queensland, 20 Cornwall Street, Woolloongabba, QLD 4102, Australia.

School of the Environment, Faculty of Science, The University of Queensland, Australia.

出版信息

Sci Total Environ. 2024 Apr 10;920:170987. doi: 10.1016/j.scitotenv.2024.170987. Epub 2024 Feb 15.

Abstract

The mounting issue of plastic waste in the aquatic ecosystem is a growing source of concern. Most plastic waste originates on land and a significant proportion of this eventually finds its way into the marine environment, which is widely regarded as a major repository for plastic debris. Currently, there exists a substantial gap in our understanding of how much plastic, the main polymer types, and the distribution of plastic in the marine environment. This study aimed to provide information on mass concentrations of a range of plastics in the surface sediments in the semi-enclosed Moreton Bay, just offshore the large city of Brisbane, Southeast Queensland, Australia. Surface sediment samples were quantitatively analysed for a suite of 7 common plastic polymer types (i.e., polystyrene (PS), polycarbonate (PC), poly-(methyl methacrylate) (PMMA), polypropylene (PP), polyethylene terephthalate (PET), polyethylene (PE) and polyvinyl chloride (PVC)) using a pressurized liquid extraction (PLE) followed by double-shot microfurnace pyrolysis coupled to gas chromatography mass spectrometry (Pyr-GC/MS). The advantage of this approach is that it can measure plastics below the limit of visual detection. The study revealed that Σplastics were consistently present in the samples, although the concentrations displayed a wide range of concentrations from 3.3 to 2194.2 μg/g across different sites. Among the polymers analysed, PE and PVC were found at the highest concentrations, ranging from 2.3 to 1885.9 μg/g and 3.0-979.5 μg/g, respectively. Based on the average concentrations of plastics measured, the dry bulk density and volume of sediments within the top 10 cm of the bay, it was estimated that there is a minimum of 7000 t of plastics stored in the surface sediments of the bay. This study is the first to report the mass concentrations of identified plastics and identify the main polymer types in Moreton Bay. This is important information to develop management plans to reduce the plastic waste entering the coastal marine environment.

摘要

水生生态系统中塑料垃圾问题日益严重,引发了越来越多的关注。大多数塑料垃圾源自陆地,其中很大一部分最终进入海洋环境,海洋被广泛视为塑料碎片的主要储存库。目前,我们对海洋环境中塑料的数量、主要聚合物类型以及塑料分布的了解存在很大差距。本研究旨在提供有关澳大利亚昆士兰州东南部大城市布里斯班近海半封闭的摩顿湾表层沉积物中一系列塑料的质量浓度信息。使用加压液体萃取(PLE),然后进行双喷微炉热解并与气相色谱 - 质谱联用(Pyr - GC/MS),对表层沉积物样本中的7种常见塑料聚合物类型(即聚苯乙烯(PS)、聚碳酸酯(PC)、聚甲基丙烯酸甲酯(PMMA)、聚丙烯(PP)、聚对苯二甲酸乙二酯(PET)、聚乙烯(PE)和聚氯乙烯(PVC))进行定量分析。这种方法的优点是可以测量低于目视检测限的塑料。研究表明,样本中始终存在Σ塑料,尽管不同地点的浓度范围很广,从3.3到2194.2μg/g不等。在所分析的聚合物中,PE和PVC的浓度最高,分别为2.3至1885.9μg/g和3.0 - 979.5μg/g。根据所测量的塑料平均浓度、海湾顶部10厘米内沉积物的干容重和体积,估计海湾表层沉积物中至少储存了7000吨塑料。本研究首次报告了摩顿湾中已识别塑料的质量浓度,并确定了主要聚合物类型。这是制定管理计划以减少进入沿海海洋环境的塑料垃圾的重要信息。

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