Stepancikova Romana, Olejnik Robert, Matyas Jiri, Masar Milan, Hausnerova Berenika, Slobodian Petr
Centre of Polymer Systems, University Institute, Tomas Bata University, Trida T. Bati 5678, 76001 Zlin, Czech Republic.
Department of Production Engineering, Faculty of Technology, Tomas Bata University in Zlin, Vavreckova 5669, 76001 Zlin, Czech Republic.
Sensors (Basel). 2024 Feb 17;24(4):1275. doi: 10.3390/s24041275.
This study reports the possibility of using biaxially oriented polyethylene terephthalate (BOPET) plastic packaging to convert mechanical energy into electrical energy. Electricity is generated due to the piezoelectricity of BOPET. Electricity generation depends on the mechanical deformation of the processing aids (inorganic crystals), which were found and identified by SEM and EDAX analyses as SiO. BOPET, as an electron source, was assembled and tested as an energy conversion and self-powered mechanical stimuli sensor using potential applications in wearable electronics. When a pressure pulse after pendulum impact with a maximum stress of 926 kPa and an impact velocity of 2.1 m/s was applied, a voltage of 60 V was generated with short-circuit current and charge densities of 15 μAcm and 138 nCm, respectively. Due to the orientation and stress-induced crystallization of polymer chains, BOPET films acquire very good mechanical properties, which are not lost during their primary usage as packaging materials and are beneficial for the durability of the sensors. The signals detected using BOPET sensors derived from pendulum impact and sieve analyses were also harvested for up to 80 cycles and up to 40 s with short-circuit voltages of 107 V and 95 V, respectively. In addition to their low price, the advantage of sensors made from BOPET plastic packaging waste lies in their chemical resistance and stability under exposure to oxygen, ultraviolet light, and moisture.
本研究报告了使用双向拉伸聚对苯二甲酸乙二酯(BOPET)塑料包装将机械能转化为电能的可能性。由于BOPET的压电性而产生电能。发电取决于加工助剂(无机晶体)的机械变形,通过扫描电子显微镜(SEM)和能谱分析(EDAX)发现并确定其为SiO。作为电子源的BOPET被组装并作为能量转换和自供电机械刺激传感器进行测试,用于可穿戴电子产品的潜在应用。当施加摆锤冲击后最大应力为926 kPa、冲击速度为2.1 m/s的压力脉冲时,产生了60 V的电压,短路电流和电荷密度分别为15 μA/cm和138 nC/cm。由于聚合物链的取向和应力诱导结晶,BOPET薄膜具有非常好的机械性能,在其作为包装材料的初次使用过程中不会丧失,并且有利于传感器的耐久性。使用BOPET传感器从摆锤冲击和筛分分析中检测到的信号也分别在短路电压为107 V和95 V的情况下采集了长达80个周期和40秒。除了价格低廉之外,由BOPET塑料包装废料制成的传感器的优点还在于其耐化学性以及在暴露于氧气、紫外线和湿气时的稳定性。