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四 - 双 -(μ - 2 - 羟基 - 3,5 - 二异丙基苯甲酸根)双 - [(二甲基亚砜)铜(II)]的晶体结构

Crystal structure of tetra-kis-(μ-2-hy-droxy-3,5-di-isoprop-yl-benzoato)bis-[(dimethyl sulfoxide)copper(II)].

作者信息

Shlian Daniel G, Summers Rachael H, Martinez Katelyn, Upmacis Rita K

机构信息

Department of Chemistry, Columbia University, New York, NY 10027, USA.

Department of Chemistry & Physical Sciences, Pace University, New York, NY 10038, USA.

出版信息

Acta Crystallogr E Crystallogr Commun. 2024 Feb 27;80(Pt 3):335-338. doi: 10.1107/S205698902400166X. eCollection 2024 Mar 1.

Abstract

Metal complexes of 3,5-diiso-propyl-salicylate are reported to have anti-inflammatory and anti-convulsant activities. The title binuclear copper complex, [Cu(CHO)(CHOS)] or [Cu(II)(3,5-DIPS)(DMSO)], contains two five-coordinate copper atoms that are bridged by four 3,5-diiso-propyl-salicylate ligands and capped by two axial dimethyl sulfoxide (DMSO) moieties. Each copper atom is attached to four oxygen atoms in an almost square-planar fashion, with the addition of a DMSO ligand in an apical position leading to a square-pyramidal arrangement. The hy-droxy group of the diiso-propyl-salicylate ligands participates in intra-molecular O-H⋯O hydrogen-bonding inter-actions.

摘要

据报道,3,5-二异丙基水杨酸的金属配合物具有抗炎和抗惊厥活性。标题双核铜配合物[Cu(CHO)(CHOS)]或[Cu(II)(3,5-DIPS)(DMSO)]包含两个五配位铜原子,它们由四个3,5-二异丙基水杨酸配体桥联,并由两个轴向二甲基亚砜(DMSO)部分封端。每个铜原子以几乎平面正方形的方式与四个氧原子相连,在顶端位置添加一个DMSO配体导致形成四方锥排列。二异丙基水杨酸配体的羟基参与分子内O-H⋯O氢键相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a9d/10915660/cb9a4754c9df/e-80-00335-fig1.jpg

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