Lv Jiaxin, Zhang Chaoneng, Qu Guangfei, Pan Keheng, Qin Jin, Wei Kunling, Liang Yuqi
Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Yunnan, 650500, China; National Regional Engineering Research Center-NCW, Yunnan, 650500, China.
Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Yunnan, 650500, China; National Regional Engineering Research Center-NCW, Yunnan, 650500, China.
Talanta. 2024 Jun 1;273:125853. doi: 10.1016/j.talanta.2024.125853. Epub 2024 Feb 29.
Semiconductor metal oxides (SMOs) nanomaterials are a category of sensing materials that are widely applied to chemiresistive NO gas sensors. However, there is much space to improve the sensing performance of SMOs nanomaterials. Therefore, how to improve the sensing performance of SMOs nanomaterials for NO gases has always attracted the interest of researchers. Up to now, there are few reviews focus on the modification strategies of SMOs which applied to NO gas sensors. In order to compensate for the limitation, this review summarizes the existing modification strategies of SMOs, hoping to provide researchers a view of the research progress in this filed as comprehensive as possible. This review focuses on the progress of the modification of SMOs nanomaterials for chemiresistive NO (NO, NO) gas sensors, including the morphology modulation of SMOs, compositing SMOs, loading noble metals, doping metal ions, compositing with carbon nanomaterials, compositing with biomass template, and compositing with MXene, MOFs, conducting polymers. The mechanism of each strategy to enhance the NO sensing performance of SMOs-based nanomaterials is also discussed and summarized. In addition, the limitations of some of the modification strategies and ways to address them are discussed. Finally, future perspectives for SMOs-based NO gas sensors are also discussed.
半导体金属氧化物(SMOs)纳米材料是一类广泛应用于化学电阻型NO气体传感器的传感材料。然而,提高SMOs纳米材料的传感性能仍有很大空间。因此,如何提高SMOs纳米材料对NO气体的传感性能一直吸引着研究人员的兴趣。到目前为止,很少有综述关注应用于NO气体传感器的SMOs的改性策略。为了弥补这一不足,本综述总结了现有的SMOs改性策略,希望能为研究人员提供该领域尽可能全面的研究进展。本综述重点介绍了用于化学电阻型NO(NO,NO)气体传感器的SMOs纳米材料的改性进展,包括SMOs的形貌调控、与SMOs复合、负载贵金属、掺杂金属离子、与碳纳米材料复合、与生物质模板复合以及与MXene、MOFs、导电聚合物复合。还对每种提高基于SMOs的纳米材料NO传感性能的策略的机理进行了讨论和总结。此外,还讨论了一些改性策略的局限性及其解决方法。最后,还讨论了基于SMOs的NO气体传感器的未来前景。