Yan Renwei, Wang Laifa, Ni Yongjun, Zhang Shuowen, He Zhenqing, Guan Bowen
Qinghai Guoluo Highway Engineering Construction Co., Ltd., Xining 810021, China.
Qinghai Provincial Traffic Control Construction Engineering Group Co., Ltd., Xining 810001, China.
Polymers (Basel). 2024 Mar 4;16(5):697. doi: 10.3390/polym16050697.
To solve the problem of the poor abrasion resistance of concrete pavement surface mortar, this study substituted cement with equal amounts of styrene-butadiene rubber (SBR) latex and silica fume (SF) to investigate the effects of organic/inorganic material composite modification on the fluidity, drying shrinkage, mechanical properties, and abrasion resistance of cement mortar. Also in this study, the microstructure, product, and pore structure characteristics of the composite modified cement mortar were investigated using scanning electron microscope (SEM), X-Ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), and the Brunauer-Emmett-Teller (BET) method. This research found that the sole substitution of SF negatively impacted the mortar's fluidity and drying shrinkage yet enhanced its mechanical strength and abrasion resistance; the incorporation of SBR latex improved fluidity, reduced shrinkage, and increased flexural strength but adversely affected the compressive strength of the mortar. Additionally, the enhancement of the mortar's abrasion resistance with SBR latex was significantly greater than that with SF. When SBR latex and SF were used together as substitutes, the latex struggled to offset the negative impact of SF on mortar fluidity but effectively reduced shrinkage; SF compensated for the detrimental effect of the latex on compressive strength. Moreover, the primary role in enhancing the mortar's abrasion resistance was played by the latex. Microscopic tests showed that SBR latex and SF could increase the content of calcium silicate hydrate (C-S-H) gel, inhibit the formation of ettringite (AFt) and reduce carbonation, refine the pore size of cement mortar, and effectively improve the microstructure of mortar.
为解决混凝土路面表层砂浆耐磨性差的问题,本研究用等量的丁苯橡胶(SBR)乳液和硅灰(SF)替代水泥,以研究有机/无机材料复合改性对水泥砂浆流动性、干燥收缩、力学性能和耐磨性的影响。此外,本研究还采用扫描电子显微镜(SEM)、X射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)和布鲁诺尔-埃米特-泰勒(BET)法研究了复合改性水泥砂浆的微观结构、产物和孔隙结构特征。本研究发现,单独使用SF会对砂浆的流动性和干燥收缩产生负面影响,但会提高其机械强度和耐磨性;掺入SBR乳液可改善流动性、减少收缩并提高抗弯强度,但会对砂浆的抗压强度产生不利影响。此外,SBR乳液对砂浆耐磨性的增强作用明显大于SF。当SBR乳液和SF一起用作替代品时,乳液难以抵消SF对砂浆流动性的负面影响,但能有效减少收缩;SF弥补了乳液对抗压强度的不利影响。此外,增强砂浆耐磨性的主要作用由乳液发挥。微观测试表明,SBR乳液和SF可增加水化硅酸钙(C-S-H)凝胶的含量,抑制钙矾石(AFt)的形成并减少碳化,细化水泥砂浆的孔径,并有效改善砂浆的微观结构。