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骆驼粪便衍生生物炭用于去除水溶液中的铜(II)和铬(III)离子:吸附与动力学研究

Camel Dung-Derived Biochar for the Removal of Copper(II) and Chromium(III) Ions from Aqueous Solutions: Adsorption and Kinetics Studies.

作者信息

Wilson Kenesha, Iqbal Jibran, Obaid Abdalla Obaid Hableel Amira, Naji Khalaf Beyaha Alzaabi Zainab, Nazzal Yousef

机构信息

College of Natural and Health Sciences, Zayed University, Abu Dhabi, UAE.

出版信息

ACS Omega. 2024 Feb 27;9(10):11500-11509. doi: 10.1021/acsomega.3c08230. eCollection 2024 Mar 12.

Abstract

This study explores an innovative approach to tackle the critical issue of heavy metal ion contamination in aqueous solutions through the utilization of camel dung-derived biochar. In the context of global environmental concerns and the adverse impacts of heavy metal pollution on ecosystems and human health, the investigation focuses on copper(II) and chromium(III) ions, which are among the most pervasive pollutants originating from industrial activities. The research revealed that camel dung-derived biochar exhibits exceptional potential for the removal of copper(II) and chromium(III) ions, with removal efficiencies of more than 90% and adsorption capacities of 23.20 and 23.36 mg/g, respectively. The adsorption processes followed second-order kinetics, and the data fitted both the Langmuir and Freundlich adsorption models. The underlying mechanisms governing this adsorption phenomenon seem to be grounded in complexation reactions, cation exchange, and cation-π interactions, underscoring the multifaceted nature of the interactions between the biochar and heavy metal ions. This research not only advances our understanding of sustainable materials for water purification but also harnesses the underutilized potential of camel dung as a valuable resource for environmental remediation, offering a promising avenue for addressing global water pollution challenges.

摘要

本研究探索了一种创新方法,通过利用骆驼粪便衍生的生物炭来解决水溶液中重金属离子污染这一关键问题。在全球环境问题以及重金属污染对生态系统和人类健康的不利影响的背景下,该研究聚焦于铜(II)和铬(III)离子,它们是源自工业活动的最普遍污染物之一。研究表明,骆驼粪便衍生的生物炭在去除铜(II)和铬(III)离子方面具有卓越潜力,去除效率分别超过90%,吸附容量分别为23.20和23.36 mg/g。吸附过程遵循二级动力学,数据符合朗缪尔和弗伦德利希吸附模型。控制这种吸附现象的潜在机制似乎基于络合反应、阳离子交换和阳离子-π相互作用,突出了生物炭与重金属离子之间相互作用的多面性。这项研究不仅增进了我们对用于水净化的可持续材料的理解,还利用了骆驼粪便作为环境修复宝贵资源的未充分利用潜力,为应对全球水污染挑战提供了一条有前景的途径。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5621/10938451/4342b241957b/ao3c08230_0001.jpg

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