Sb(V) dihalide corroles: efficient singlet oxygen photosensitisers.
作者信息
Caliskanyürek Volkan, Eulberg Simon, Lange Oliver, Bröring Martin, Tschierlei Stefanie
机构信息
Department of Energy Conversion, Institute of Physical and Theoretical Chemistry, Technische Universität Braunschweig, Rebenring 31, 38106, Braunschweig, Germany.
Institute of Inorganic and Analytical Chemistry, Technische Universität Braunschweig, Hagenring 30, 38106, Braunschweig, Germany.
出版信息
Chem Commun (Camb). 2024 Apr 9;60(30):4096-4099. doi: 10.1039/d4cc00675e.
Sb(V) dihalide corrole complexes, in particular difluoro-5,15-di(4-cyanophenyl)-10-(2,4,5-trimethoxyphenyl)corrolatoantimony(V) (complex 1), show distinct emission properties and efficient intersystem crossing rates. Furthermore, complex 1 is characterised by its extended triplet excited state lifetime and an impressive singlet oxygen quantum yield exceeding 95%. This emphasises its potential for effective photooxidation reactions, positioning it as a leader in Sb(V) complex applications.
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