Abdullah Mohd Na'im, Mustapha Faizal, Yusof Nurul 'Izzati, Khan Tabrej, Sebaey Tamer A
Department of Aerospace Engineering, Faculty of Engineering, Universiti Putra Malaysia, Serdang 43400, Malaysia.
Engineering Management Department, College of Engineering, Prince Sultan University, P.O. Box 66833, Riyadh 11586, Saudi Arabia.
Materials (Basel). 2024 Mar 11;17(6):1298. doi: 10.3390/ma17061298.
This study aims to develop suitable formulations of geopolymer concrete (GPC) by varying the percentages of the geopolymer with aggregates and evaluating the performances in thermal and mechanical properties of palm kernel shell ash (PKSA)-GPC compared to rice husk ash (RHA)-GPC and ordinary Portland cement concrete (OPCC). Preliminary tests were conducted to select the best mix design ratios before casting the specimens. Then, the performance of the PKSA-GPC, RHA-GPC and OPCC specimens was evaluated based on their thermal performance and drying shrinkage. The mix designs of PKSA-GPC 70:30, PKSA-GPC 60:40, PKSA-GPC 50:50 and PKSA-GPC 66.6:33.3 were found to produce an acceptable consistency, rheological and thixotropic behaviour for the development of the GPC. PKSA-GPC showed a better thermal performance than the RHA-GPC and OPCC due to their strong and dense intumescent layers and slow temperature increment upon exposure to a high flame temperature from ambient temperature to 169 °C. The low molar ratio of the Si/Al present in the PKSA-GPC created a thermally stable intumescent layer. In the drying shrinkage test, PKSA-GPC 60:40 and RHA-GPC 60:40 shared an equal drying shrinkage performance (5.040%) compared to the OPCC (8.996%). It was observed that microcrack formation could significantly contribute to the high shrinkage in the PKSA-GPC 50:50 and RHA-GPC 70:30 specimens. The findings of this study show that PKSA could be incorporated into GPC as a fire-retardant material due to its capability of prolonging the spread of fire upon ignition and acting as an alternative to the conventional OPCC.
本研究旨在通过改变地质聚合物与骨料的百分比来开发合适的地质聚合物混凝土(GPC)配方,并评估棕榈壳灰(PKSA)-GPC与稻壳灰(RHA)-GPC和普通硅酸盐水泥混凝土(OPCC)相比在热性能和力学性能方面的表现。在浇筑试件之前进行了初步试验,以选择最佳配合比设计。然后,根据PKSA-GPC、RHA-GPC和OPCC试件的热性能和干燥收缩来评估其性能。发现PKSA-GPC 70:30、PKSA-GPC 60:40、PKSA-GPC 50:50和PKSA-GPC 66.6:33.3的配合比设计对于GPC的开发具有可接受的稠度、流变学和触变性行为。PKSA-GPC由于其强大而致密的膨胀层以及在从环境温度到169°C的高火焰温度下温度上升缓慢,显示出比RHA-GPC和OPCC更好的热性能。PKSA-GPC中低的硅铝摩尔比形成了热稳定的膨胀层。在干燥收缩试验中,PKSA-GPC 60:40和RHA-GPC 60:40具有相同的干燥收缩性能(5.040%),而OPCC为8.996%。观察到微裂纹的形成可能是导致PKSA-GPC 50:50和RHA-GPC 70:30试件高收缩的重要原因。本研究结果表明,PKSA可作为一种阻燃材料掺入GPC中,因为它能够在着火时延长火势蔓延,并可作为传统OPCC的替代品。