Li Qing, Li Nan, Zhi Chunyi
Department of Materials Science and Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong SAR 999077, People's Republic of China.
Hong Kong Center for Cerebro-Cardiovascular Health Engineering (COCHE), Shatin, New Territories, Hong Kong SAR 999077, People's Republic of China.
Nano Lett. 2024 Apr 10;24(14):4055-4063. doi: 10.1021/acs.nanolett.4c00101. Epub 2024 Mar 30.
Aqueous rechargeable zinc-based batteries hold great promise for energy storage applications, with most research utilizing zinc foils as the anode. Conversely, the high tunability of zinc powder (Zn-P) makes it an ideal choice for zinc-based batteries, seamlessly integrating with current battery production technologies. However, challenges such as contact loss, dendrite formation, and a high tendency for corrosion significantly hamper the performance enhancement of Zn-P anodes. This review provides an overview of strategies adopted from various perspectives, including zinc powder optimization, electrode engineering, and electrolyte modification, to address these issues. Additionally, it explores the limitations of existing research and offers valuable insights into potential future directions for further advancements in Zn-P anodes.
水系可充电锌基电池在储能应用方面具有巨大潜力,大多数研究都使用锌箔作为负极。相反,锌粉(Zn-P)的高度可调性使其成为锌基电池的理想选择,能够与当前的电池生产技术无缝集成。然而,诸如接触损耗、枝晶形成和高腐蚀倾向等挑战严重阻碍了Zn-P负极性能的提升。本综述从锌粉优化、电极工程和电解质改性等多个角度概述了为解决这些问题而采用的策略。此外,还探讨了现有研究的局限性,并为Zn-P负极未来进一步发展的潜在方向提供了有价值的见解。