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基于聚偏二氟乙烯的摩擦纳米发电机中,源自人发生物废弃物的纳米结构碳的光致电荷产生,用于性能提升。

Photoinduced charge generation of nanostructured carbon derived from human hair biowaste for performance enhancement in polyvinylidene fluoride based triboelectric nanogenerator.

机构信息

Materials Science and Nanotechnology Program, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand.

Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand; Institute of Nanomaterials Research and Innovation for Energy (IN-RIE), Khon Kaen University, Khon Kaen 40002, Thailand.

出版信息

J Colloid Interface Sci. 2024 Jul;665:720-732. doi: 10.1016/j.jcis.2024.03.170. Epub 2024 Mar 27.

Abstract

Carbon nanostructures derived from human hair biowaste are incorporated into polyvinylidene fluoride (PVDF) polymer to enhance the energy conversion performance of a triboelectric nanogenerator (TENG). The PVDF filled with activated carbon nanomaterial from human hair (AC-HH) exhibits improved surface charge density and photoinduced charge generation. These remarkable properties are attributed to the presence of graphene-like nanostructures in AC-HH, contributing to the augmented performance of PVDF@AC-HH TENG. The correlation of surface morphologies, surface charge potential, charge capacitance properties, and TENG electrical output of the PVDF composites at various AC-HH loading is studied and discussed. Applications of the PVDF@AC-HH TENG as a power source for micro/nanoelectronics and a movement sensor for detecting finger gestures are also demonstrated. The photoresponse property of the fabricated TENG is demonstrated and analyzed in-depth. The analysis indicates that the photoinduced charge carriers originate from the conductive reduced graphene oxide (rGO), contributing to the enhanced surface charge density of the PVDF composite film. This research introduces a novel approach to enhancing TENG performance through the utilization of carbon nanostructures derived from human biowaste. The findings of this work are crucial for the development of innovative energy-harvesting technology with multifunctionality, including power generation, motion detection, and photoresponse capabilities.

摘要

从人发生物废料中衍生的碳纳米结构被纳入聚偏二氟乙烯 (PVDF) 聚合物中,以提高摩擦电纳米发电机 (TENG) 的能量转换性能。填充有来自人发的活性炭纳米材料的 PVDF (AC-HH) 表现出改善的表面电荷密度和光致电荷产生。这些显著的性质归因于 AC-HH 中存在类石墨烯纳米结构,这有助于增强 PVDF@AC-HH TENG 的性能。研究并讨论了不同 AC-HH 负载下 PVDF 复合材料的表面形貌、表面电荷电位、电荷电容特性和 TENG 电输出之间的相关性。还展示了 PVDF@AC-HH TENG 作为微/纳电子学电源和用于检测手指手势的运动传感器的应用。对所制造的 TENG 的光电响应特性进行了深入的演示和分析。分析表明,光致电荷载流子源自导电还原氧化石墨烯 (rGO),这有助于提高 PVDF 复合薄膜的表面电荷密度。本研究通过利用源自人体生物废料的碳纳米结构,提出了一种增强 TENG 性能的新方法。这项工作的发现对于开发具有多功能性的创新能量收集技术至关重要,包括发电、运动检测和光电响应能力。

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