College of Textiles Science and Engineering, Wuhan Textile University, Wuhan 430200, China.
College of Textiles Science and Engineering, Wuhan Textile University, Wuhan 430200, China; Hubei Key Laboratory of Biomass Fibers and Eco-Dyeing & Finishing, Wuhan Textile University, Wuhan 430200, China.
Int J Biol Macromol. 2024 May;267(Pt 1):131444. doi: 10.1016/j.ijbiomac.2024.131444. Epub 2024 Apr 6.
Ramie bone (RB), an agricultural waste generated in the textile industry, is a vastly productive renewable natural resource with the potential to be used as a source of cellulose. In this study, ramie bone cellulose (RB-CE) was obtained in one step using a simple and ecologically friendly hydrogen peroxide-citric acid (HPCA) treatment procedure that avoided the use of halogenated reagents and strong acids while also streamlining the treatment processes. Various analytical methods were used to investigate the chemical composition and structure, crystallinity, morphology, thermal properties, surface area and hydration properties of cellulose separated at different treatment temperatures. HPCA successfully removed lignin and hemicellulose from RB, according to chemical composition analysis and FTIR. RB-CE had a type I cellulose crystal structure, and the crystallinity improved with increasing treatment temperature, reaching 72.51 % for RB-CE90. The RB-CE showed good thermal stability with degradation temperatures ranging from 294.2 °C to 319.1 °C. Furthermore, RB-CE had a high water/oil binding capacity, with RB-CE90 having WHC and OBC of 9.68 g/g and 7.24 g/g, respectively. The current work serves as a model for the environmentally friendly and convenient extraction of cellulose from biomass, and the cellulose obtained can be employed in the field of food and composite materials.
苎麻骨(RB)是纺织工业产生的农业废料,是一种具有巨大生产力的可再生天然资源,具有用作纤维素来源的潜力。在这项研究中,采用简单且环保的过氧化氢-柠檬酸(HPCA)处理工艺,一步法获得了苎麻骨纤维素(RB-CE),避免了使用卤化试剂和强酸,同时简化了处理工艺。采用各种分析方法研究了不同处理温度下分离得到的纤维素的化学成分和结构、结晶度、形态、热性能、比表面积和水合性能。根据化学成分分析和 FTIR,HPCA 成功地从 RB 中去除了木质素和半纤维素。RB-CE 具有 I 型纤维素晶体结构,结晶度随处理温度的升高而提高,在 RB-CE90 时达到 72.51%。RB-CE 具有良好的热稳定性,降解温度范围为 294.2°C 至 319.1°C。此外,RB-CE 具有较高的油水结合能力,RB-CE90 的 WHC 和 OBC 分别为 9.68g/g 和 7.24g/g。本工作为从生物质中环保、便捷地提取纤维素提供了一个模型,所得纤维素可应用于食品和复合材料领域。