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“一键重启”:无金属钙钛矿X射线探测器的循环利用

"One-Click Restart" Recycling of Metal-Free Perovskite X-Ray Detectors.

作者信息

Li Haojin, Li Telun, Ma Chuang, Liu Xinmei, Lang Lei, Yang Tinghuan, Song Xin, Cui Qingyue, Yang Zhou, Liu Shengzhong Frank, Zhao Kui

机构信息

Key Laboratory of Applied Surface and Colloid Chemistry, National Ministry of Education, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Lab for Advanced Energy Technology, Institute for Advanced Energy Materials, School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119, China.

Dalian National Laboratory for Clean Energy, iChEM, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China.

出版信息

Adv Mater. 2024 Jun;36(26):e2400783. doi: 10.1002/adma.202400783. Epub 2024 Apr 22.

Abstract

Halide perovskites have shown great potential in X-ray detection due to outstanding optoelectronic properties. However, finding a cost-effective and environmentally sustainable method for handling end-of-life devices has remained challenging. Here, a "One-Click Restart" eco-friendly recycling strategy is introduced for end-of-life perovskite X-ray detectors. This method, utilizing water, allows for the recapture and reuse of both perovskite and conductor materials. The process is straightforward and environmentally friendly, eliminating the need for further chemical treatment, purification, additional additives or catalysts, and complex equipment. A sustainable device cycle is developed by reconstructing flexible perovskite membranes for wearable electronics from recycled materials. Large-scale, flexible membranes made from metal-free perovskite DABCO-NH-I (DABCO = N-N'-diazabicyclo[2.2.2]octonium) achieve remarkably impressive average sensitivity of 6204 ± 268 µC Gy  cm and a low detection limit of 102.3 nGy s, which makes highly effective for X-ray imaging. The sensitivity of recycled flexible devices not only matches that of single-crystal devices made with fresh materials but also ranks as the highest among all metal-free perovskite X-ray detectors. "One-Click Restart" applies to scalable flexible devices derived from aged single-crystal counterparts, offering significant cost, time, and energy savings compared to their single-crystal equivalents. Such advantages significantly boost future market competitiveness.

摘要

卤化物钙钛矿由于其出色的光电特性,在X射线检测中展现出了巨大潜力。然而,找到一种经济高效且环境可持续的方法来处理报废设备仍然具有挑战性。在此,针对报废的钙钛矿X射线探测器,引入了一种“一键重启”的环保回收策略。该方法利用水,能够重新获取并再利用钙钛矿和导体材料。此过程简单直接且环保,无需进一步的化学处理、提纯、添加额外添加剂或催化剂,也无需复杂设备。通过用回收材料重建用于可穿戴电子产品的柔性钙钛矿膜,开发出了一个可持续的设备循环。由无金属钙钛矿DABCO-NH-I(DABCO = N-N'-二氮杂双环[2.2.2]辛鎓)制成的大规模柔性膜实现了令人瞩目的平均灵敏度,为6204±268 µC Gy cm,检测限低至102.3 nGy s,这使其对X射线成像非常有效。回收的柔性设备的灵敏度不仅与用新鲜材料制成的单晶设备相当,而且在所有无金属钙钛矿X射线探测器中排名最高。“一键重启”适用于由老化的单晶同类产品衍生而来的可扩展柔性设备,与单晶同类产品相比,可显著节省成本、时间和能源。这些优势显著提升了未来的市场竞争力。

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