Liu Xingbei, Zhang Chao, Yu Huanan, Qian Guoping, Zheng Xiaoguang, Zhou Hongyu, Huang Lizhang, Zhang Feng, Zhong Yixiong
School of Traffic and Transportation Engineering, National Engineering Research Center of Highway Maintenance Technology, Changsha University of Science & Technology, Changsha 410114, China.
Shanghai Municipal Engineering Design & Research Institute (Group) Co., Ltd., Shanghai 200092, China.
Materials (Basel). 2024 Mar 28;17(7):1555. doi: 10.3390/ma17071555.
To promote the resource utilization of steel slag and improve the production process of steel slag in steelmaking plants, this research studied the characteristics of three different processed steel slags from four steelmaking plants. The physical and mechanical characteristics and volume stability of steel slags were analyzed through density, water absorption, and expansion tests. The main mineral phases, morphological characteristics, and thermal stability of the original steel slag and the steel slag after the expansion test are analyzed with X-ray diffractometer (XRD), scanning electron microscope (SEM), and thermogravimetric analysis (TG) tests. The results show that the composition of steel slag produced by different processes is similar. The main active substances of other processed steel slags are dicalcium silicate (CS), tricalcium silicate (CS), CaO, and MgO. After the expansion test, the main chemical products of steel slag are CaCO, MgCO, and calcium silicate hydrate (C-S-H). Noticeable mineral crystals appeared on the surface of the steel slag after the expansion test, presenting tetrahedral or cigar-like protrusions. The drum slag had the highest density and water stability. The drum slag had the lowest porosity and the densest microstructure surface, compared with steel slags that other methods produce. The thermal stability of steel slag treated by the hot splashing method was relatively higher than that of steel slag treated by the other two methods.
为促进钢渣资源利用,改善炼钢厂钢渣生产工艺,本研究对来自四家炼钢厂的三种不同加工钢渣的特性进行了研究。通过密度、吸水率和膨胀试验分析了钢渣的物理力学特性和体积稳定性。利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)和热重分析(TG)试验,分析了原状钢渣及膨胀试验后钢渣的主要矿物相、形态特征和热稳定性。结果表明,不同工艺生产的钢渣成分相似。其他加工钢渣的主要活性物质为硅酸二钙(CS)、硅酸三钙(CS)、CaO和MgO。膨胀试验后,钢渣的主要化学产物为CaCO、MgCO和水化硅酸钙(C-S-H)。膨胀试验后钢渣表面出现明显的矿物晶体,呈四面体或雪茄状突起。滚筒渣密度最高,水稳定性最好。与其他方法生产的钢渣相比,滚筒渣孔隙率最低,微观结构表面最致密。热泼法处理钢渣的热稳定性相对高于其他两种方法处理的钢渣。