Abd El Maksoud Samir, Fouda Abd El Aziz, Badawy Haby
Department of Chemistry, Faculty of Science, Port Said University, Port Said, Egypt.
Department of Chemistry, Faculty of Science, Mansoura University, Mansoura, 35516, Egypt.
Sci Rep. 2024 Apr 20;14(1):9052. doi: 10.1038/s41598-024-58713-4.
Furosemide (4-chloro-2-furan-2-ylmethylamino-5-sulfamoylbenzoic acid) was examined as an inhibitor for the corrosion of carbon steel (CS) in 1.0 M HCl. The investigation included mass loss (ML) and electrochemical techniques: potentiodynamic polarization (PP), electrochemical impedance spectroscopy (EIS), and electrochemical frequency modulation (EFM). The efficiency of inhibition rises with increasing Furosemide concentration and temperature. This compound follows the Temkin isotherm with good fit. The presence of varying quantities influences both anodic metal dissolution and cathodic hydrogen evolution. Scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopy (FT-IR) were used to detect the effect of the compound on the CS surface. The molecular inhibitory effect of Furosemide was demonstrated using quantum chemical calculations, and the molecular simulation results demonstrated the adsorption on the carbon steel surface.
研究了呋塞米(4-氯-2-呋喃-2-基甲基氨基-5-氨磺酰基苯甲酸)作为1.0 M盐酸中碳钢(CS)腐蚀抑制剂的性能。研究包括质量损失(ML)和电化学技术:动电位极化(PP)、电化学阻抗谱(EIS)和电化学频率调制(EFM)。缓蚀效率随呋塞米浓度和温度的升高而提高。该化合物符合Temkin等温线,拟合良好。不同数量的存在会影响阳极金属溶解和阴极析氢。使用扫描电子显微镜(SEM)、原子力显微镜(AFM)、X射线光电子能谱(XPS)和傅里叶变换红外光谱(FT-IR)来检测该化合物对CS表面的影响。通过量子化学计算证明了呋塞米的分子抑制作用,分子模拟结果表明其在碳钢表面的吸附。