College of Textiles & Clothing, Institute of Functional Textiles and Advanced Materials, National Engineering Research Center for Advanced Fire-Safety Materials D & A (Shandong), Qingdao Key Laboratory of Flame Retardant Textile Materials, State Key Laboratory of Bio-Fibers and Eco-textiles, Qingdao University, Qingdao 266071, China; Shandong Foreign Trade Vocational College, Qingdao 266071, China.
College of Textiles & Clothing, Institute of Functional Textiles and Advanced Materials, National Engineering Research Center for Advanced Fire-Safety Materials D & A (Shandong), Qingdao Key Laboratory of Flame Retardant Textile Materials, State Key Laboratory of Bio-Fibers and Eco-textiles, Qingdao University, Qingdao 266071, China.
Int J Biol Macromol. 2024 May;268(Pt 1):131750. doi: 10.1016/j.ijbiomac.2024.131750. Epub 2024 Apr 22.
Applications for cotton fabrics with multifunctional qualities, such as flame retardancy, hydrophobicity, and anti-ultraviolet properties, are increasingly common and growing daily. The primary objective of this study is to investigate the preparation of flame retardant, hydrophobic, and ultraviolet (UV) protection cotton fabrics through the utilization of Poly-dimethylsiloxane-co-diphenylsiloxane, dihydroxy terminated (HTDMS) and ammonia phytate (AP). The flame retardancy, thermal stability, mechanical properties, anti-UV properties, air permeability and the hydrophobicity properties of coated cotton fabrics were evaluated. The results indicated that the HTDMS/AP coating was successfully deposited on the surface of cotton fabrics. The damaged length of Cotton/HTDMS/AP was 4.7 cm, and the limiting oxygen index reached 31.5 %. The thermogravimetric analysis revealed that the char residues in the high-temperature range were increased. Furthermore, cone calorimetry results indicated that after the HTDMS/AP coating, the peak heat release rate, total heat release, and total smoke production values decreased by 88.7 %, 51.2 %, and 98.4 %, respectively. Moreover, the deposition of HTDMS/AP provided cotton fabrics with hydrophobicity with a water contact angle of over 130°, while Cotton/HTDMS/AP maintained their air permeability, and enhanced the breaking force compared with those of Cotton/AP. Such desirable qualities make HTDMS/AP a meaningful coating for producing multifunctional cotton fabrics.
应用于具有多种功能的棉织物,如阻燃、疏水性和抗紫外线性能,越来越普遍,且需求日益增长。本研究的主要目的是通过使用聚二甲基硅氧烷-二苯基硅氧烷、端羟基二甲基硅氧烷(HTDMS)和植酸氨(AP)来制备阻燃、疏水和紫外线(UV)防护棉织物。评估了涂层棉织物的阻燃性、热稳定性、机械性能、抗紫外线性能、透气性和疏水性。结果表明,HTDMS/AP 涂层成功地沉积在棉织物的表面。棉/HTDMS/AP 的损毁长度为 4.7cm,极限氧指数达到 31.5%。热重分析表明,高温范围内的炭残留物增加。此外,锥形量热计结果表明,经过 HTDMS/AP 涂层后,峰值热释放率、总热释放量和总烟释放量分别降低了 88.7%、51.2%和 98.4%。此外,HTDMS/AP 的沉积为棉织物提供了疏水性,水接触角超过 130°,而棉/HTDMS/AP 保持了其空气渗透性,并提高了断裂力,与棉/AP 相比。这些理想的特性使得 HTDMS/AP 成为生产多功能棉织物的有意义的涂层。