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加速老化循环对未漂桉木纤维增强挤出水泥基复合材料性能的影响。

Impact of accelerated aging cycles on the performance of extruded cement-based composites reinforced with non-bleached eucalyptus fibers.

机构信息

Department of Production Engineering, State University of Amapá - UEAP, Av. Presidente Getúlio Vargas, N. 650, Macapá, AP, Brazil.

Institute of Agrarian Science - ICA, Rural Federal University of Amazonia, Tancredo Neves Av., 2501, Belém, PA, Zip code 66077-830, Brazil.

出版信息

Environ Sci Pollut Res Int. 2024 May;31(24):35789-35799. doi: 10.1007/s11356-024-33665-4. Epub 2024 May 14.

Abstract

Thermo-mechanical pulping produces well-individualized fibers compared to wood particles and less fragile fibers compared to Kraft pulping, besides presenting higher volume, higher yield, and lower production cost, which can be an exciting alternative for the fiber-cement industries. This study evaluated the impact of soak and dry-aging cycles on the performance of extruded composites reinforced with non-bleached eucalyptus fibers. The cement matrix comprised cement (70%) and limestone (30%). Composites were reinforced with 1 to 5% of eucalyptus fiber by cement mass and tested on the 28th day of cure at 99% relative humidity and after 400 accelerated aging cycles. The water absorption and apparent porosity gradually increased with the reinforcement level. Composites with 4 and 5% fibers showed the highest toughness (0.21 and 0.23 kJ/m, respectively). The aging by 400 soak-dry cycles reduced the composites' water absorption and apparent porosity. The modulus of elasticity (MOE), rupture (MOR), and toughness increased, except for toughness for composites reinforced with 1 and 5% fibers, explained by the cementitious matrix's continuous hydration, fiber mineralization, and natural carbonation. In general, eucalyptus thermo-mechanical fibers were suitable for producing cementitious composites. Cementitious composites with 3% fibers presented a higher MOR, MOE, low water absorption, and apparent porosity after 400 accelerated aging cycles. In addition, the composites with 4% fibers also presented remarkable improvements in these properties. The aging cycles did not result in composites with less resistance, a positive fact for their application as tiles and materials for external use in civil construction.

摘要

与木质颗粒相比,热机械浆可生产出具有良好个性化的纤维,与硫酸盐浆相比,纤维的脆性更小。此外,热机械浆的产量更高、出浆率更高、生产成本更低,这对于纤维水泥行业来说是一个令人兴奋的选择。本研究评估了浸泡和干老化循环对非漂白纸浆桉木纤维增强挤出复合材料性能的影响。水泥基质由水泥(70%)和石灰石(30%)组成。复合材料中桉木纤维的质量占水泥的 1%至 5%,在 99%相对湿度下固化 28 天后进行测试,并经过 400 次加速老化循环后进行测试。吸水率和表观孔隙度随增强水平逐渐增加。含 4%和 5%纤维的复合材料表现出最高的韧性(分别为 0.21 和 0.23kJ/m)。400 次浸泡-干燥循环老化降低了复合材料的吸水率和表观孔隙度。弹性模量(MOE)、断裂(MOR)和韧性增加,除了增强 1%和 5%纤维的复合材料的韧性外,这是由于水泥基体的持续水化、纤维的矿化和自然碳化。一般来说,桉树木质热机械纤维适合生产水泥基复合材料。含 3%纤维的水泥基复合材料经过 400 次加速老化循环后,具有更高的 MOR、MOE、低吸水率和表观孔隙率。此外,含 4%纤维的复合材料在这些性能方面也有显著提高。老化循环并没有导致复合材料的阻力降低,这对于它们在瓷砖和民用建筑外部材料中的应用是一个积极的事实。

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