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含石墨烯基添加剂的土膏药性能

Performance of Earth Plasters with Graphene-Based Additive.

作者信息

Gallo Stampino Paola, Ceccarelli Letizia, Caruso Marco, Mascheretti Laura, Dotelli Giovanni, Sabbadini Sergio

机构信息

Department of Chemistry, Materials and Chemical Engineering "G. Natta", Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan, Italy.

Materials Testing Laboratory, Politecnico di Milano, Via Celoria 3, 20133 Milan, Italy.

出版信息

Materials (Basel). 2024 May 15;17(10):2356. doi: 10.3390/ma17102356.

Abstract

A central debate is the improvement in the mechanical and water resistance of sustainable earthen architecture without additives or stabilizers. This innovative work aims to test the effects of a graphene-based additive, optimized for the improvement in concrete properties, on the strength and water resistance of raw-earth plasters without any stabilizer other than sand. Given the heterogeneous nature of raw earth, three different soils were tested by adding three increasing graphene-based additive contents (0.01, 0.05 and 0.1 wt% of the earth-sand proportion). The link between soil intrinsic properties, i.e., geotechnical and mineralogical properties, and their interaction with the additive were investigated through geotechnical characterization, as well as mineralogical characterization, by XRD and ATR-FTIR analyses. The experimental tests carried out focused on the adhesion properties of the twelve different plasters on standard hollow bricks and on their interaction with water through capillary rise tests and erosion resistance tests. Conclusion from the experimental tests suggests that the graphene-based additive in earth plasters, by increasing the cohesion of the mixture, improves their adhesion performance.

摘要

一个核心争论点在于,在不添加添加剂或稳定剂的情况下,如何提高可持续土坯建筑的机械性能和防水性能。这项创新性工作旨在测试一种为改善混凝土性能而优化的基于石墨烯的添加剂,对未添加除沙子以外任何稳定剂的生土灰泥的强度和防水性能的影响。鉴于生土的异质性,通过添加三种逐渐增加的基于石墨烯的添加剂含量(占土砂比例的0.01、0.05和0.1 wt%),对三种不同的土壤进行了测试。通过岩土特性表征以及利用XRD和ATR - FTIR分析进行的矿物学表征,研究了土壤固有特性(即岩土和矿物学特性)及其与添加剂之间的相互作用。所进行的实验测试集中于十二种不同灰泥在标准空心砖上的粘附性能,以及通过毛细上升试验和抗侵蚀试验研究它们与水的相互作用。实验测试的结论表明,土灰泥中基于石墨烯的添加剂通过增加混合物的内聚力,改善了它们的粘附性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/455a/11123424/490bd2dd9f87/materials-17-02356-g001.jpg

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