Liu Zi, Greaney Michael F
Dept of Chemistry, University of Manchester, Oxford Rd, Manchester M13 9PL, UK.
Chem Commun (Camb). 2024 Jun 13;60(49):6296-6299. doi: 10.1039/d4cc01935k.
Intermolecular aminoarylation of alkynes is described, addition of diarylanilines to alkynes and Smiles-Truce rearrangement. The transformation manipulates the C-N bond of anilines directly, with no requirement for organometallic reagents or transition metal catalysis. The enaminoate products are versatile building blocks for different classes of heterocycles.
描述了炔烃的分子间氨基芳基化反应，即二芳基苯胺与炔烃的加成反应以及斯迈尔斯-特鲁斯重排反应。该转化过程直接操控苯胺的C-N键，无需有机金属试剂或过渡金属催化。烯胺酸酯产物是用于不同类型杂环的通用结构单元。
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