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铝空气电池：当前进展与未来发展方向的前景

Aluminum-air batteries: current advances and promises with future directions.

作者信息

Rani Bharti, Yadav Jitendra Kumar, Saini Priyanka, Pandey Anant Prakash, Dixit Ambesh

机构信息

Advanced Material and Devices Laboratory (A-MAD), Department of Physics, Indian Institute of Technology Jodhpur Rajasthan 342030 India

出版信息

RSC Adv. 2024 Jun 3;14(25):17628-17663. doi: 10.1039/d4ra02219j. eCollection 2024 May 28.

DOI:10.1039/d4ra02219j
PMID:38832240
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11145468/
Abstract

Owing to their attractive energy density of about 8.1 kW h kg and specific capacity of about 2.9 A h g, aluminum-air (Al-air) batteries have become the focus of research. Al-air batteries offer significant advantages in terms of high energy and power density, which can be applied in electric vehicles; however, there are limitations in their design and aluminum corrosion is a main bottleneck. Herein, we aim to provide a detailed overview of Al-air batteries and their reaction mechanism and electrochemical characteristics. This review emphasizes each component/sub-component including the anode, electrolyte, and air cathode together with strategies to modify the electrolyte, air-cathode, and even anode for enhanced performance. The latest advancements focusing on the specific design of Al-air batteries and their rechargeability characteristics are discussed. Finally, the constraints and prospects of their use in mobility applications are also covered in depth. Thus, the present review may pave the way for researchers and developers working in energy storage solutions to look beyond lithium/sodium ion-based storage solutions.

摘要

由于铝空气（Al-air）电池具有约8.1千瓦·时/千克的诱人能量密度和约2.9安·时/克的比容量，它们已成为研究热点。铝空气电池在高能量和功率密度方面具有显著优势，可应用于电动汽车；然而，其设计存在局限性，铝腐蚀是主要瓶颈。在此，我们旨在详细概述铝空气电池及其反应机理和电化学特性。本综述着重介绍了包括阳极、电解质和空气阴极在内的每个组件/子组件，以及为提高性能而对电解质、空气阴极甚至阳极进行改性的策略。讨论了专注于铝空气电池特定设计及其可充电性特征的最新进展。最后，还深入探讨了其在移动应用中的限制和前景。因此，本综述可能为从事储能解决方案的研究人员和开发人员开辟道路，使他们超越基于锂/钠离子的储能解决方案。

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