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通过钕铁硼磁废料原位氢处理(HPMS)回收制备的商用防腐涂层的加工性能与可分离性

Processability and Separability of Commercial Anti-Corrosion Coatings Produced by In Situ Hydrogen-Processing of Magnetic Scrap (HPMS) Recycling of NdFeB.

作者信息

Grau Laura, Fleissner Peter, Kobe Spomenka, Burkhardt Carlo

机构信息

Jožef Stefan International Postgraduate School, Jamova Cesta 39, 1000 Ljubljana, Slovenia.

Institute of Precious and Technology Metals (STI), Pforzheim University, Tiefenbronner Straße 65, 75175 Pforzheim, Germany.

出版信息

Materials (Basel). 2024 May 21;17(11):2487. doi: 10.3390/ma17112487.

Abstract

The recycling of NdFeB magnets is necessary to ensure a reliable and ethical supply of rare earth elements as critical raw materials. This has been recognized internationally, prompting the implementation of large-scale legislative measured aimed at its resolution; for example, an ambitious recycling quote has been established in the Critical Raw Materials Act Successful recycling in sufficient quantities is challenged by product designs that do not allow the extraction and recycling of these high-performance permanent magnets without excessive effort and cost. This is particularly true for smaller motors using NdFeB magnets. Therefore, methods of recycling such arrangements with little or no dismantling are being researched. They are tested for the hydrogen-processing of magnetic scrap (HPMS) method, a short-loop mechanical recycling process. As contamination of the recycled material with residues of anti-corrosion coatings, adhesives, etc., may lead to downcycling, the separability of such residues from bulk magnets and magnet powder is explored. It is found that the hydrogen permeability, expansion volume, and the chosen coating affect the viable preparation and separation methods as recyclability-relevant design features.

摘要

钕铁硼磁体的回收利用对于确保稀土元素作为关键原材料的可靠且合乎道德的供应至关重要。这一点已得到国际认可,促使各国实施大规模立法措施以解决该问题;例如,《关键原材料法案》中设定了雄心勃勃的回收目标。产品设计使得在不过度费力和成本过高的情况下无法提取和回收这些高性能永磁体,这给足量的成功回收带来了挑战。对于使用钕铁硼磁体的小型电机而言尤其如此。因此,正在研究几乎无需拆解或完全无需拆解就能回收此类装置的方法。对磁废料的氢处理(HPMS)方法(一种短循环机械回收工艺)进行了测试。由于回收材料可能会被防腐涂层、粘合剂等的残留物污染,从而导致降级回收,因此探索了从块状磁体和磁粉中分离此类残留物的方法。研究发现,氢渗透率、膨胀体积以及所选涂层作为与可回收性相关的设计特征,会影响可行的制备和分离方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4605/11172457/f92ab607d969/materials-17-02487-g001.jpg

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