The influence of the doping concentration and reverse intersystem crossing on the efficiency of tricomponent organic light-emitting diodes with the thermally activated delayed fluorescence exciplex emitter.

In this work, we fabricate a series of full-fluorescent organic light-emitting diodes (OLEDs) with the thermally activated delayed fluorescence (TADF) exciplex emitter in order to improve the efficiency through the reverse intersystem crossing (RISC) process. The TADF exciplex emitters are made up of a mixture of P-type materials (DMAC-DPS and mCBP) and n-type material (PO-T2T), among which DMAC-DPS also classes as a TADF material. The change in doping concentration will affect the intermolecular distance and the composition of TADF material and two kinds of exciplexes (DMAC-DPS:PO-T2T and mCBP:PO-T2T) in the luminescent layer (EML). Different materials and concentrations of doping not only add new RISC channels but also alter the original RISC channels, thereby affecting the performance of devices. It is beneficial for improving efficiency by increasing the proportion of independent TADF material and reducing the proportion of exciplex (DMAC-DPS:PO-T2T) in the EML, which can be controlled by doping. When the ratio of DMAC-DPS, PO-T2T and mCBP in the EML is 1 : 1 : 2, we achieve the optimal electro-optic performance in device A3, with maximum current efficiency, power efficiency, and luminance of 41.64 cd A, 43.42 lm W, and 23 080 cd m, respectively.