Li Zixin, Li Donghui, Lei Wenjie, Li Zhe
State Key Laboratory Cultivation Base for Gas Geology and Gas Control, Henan Polytechnic University, Jiaozuo 454000, China.
School of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China.
ACS Omega. 2024 Jul 12;9(29):31754-31764. doi: 10.1021/acsomega.4c02850. eCollection 2024 Jul 23.
In order to investigate the electrical response characteristics of anthracite coal reservoirs and their correlation with water saturation, salinity, and porosity, the complex resistivity of Zhaogu No. 2 mine anthracite coal was measured across a frequency range of 1 Hz to 100 kHz. The experimental findings indicate that as water saturation, salinity, and porosity increase, the amplitude of both the real and imaginary components of the complex resistance of the coal sample gradually decreases, leading to a decrease in the dispersion degree and an increase in the interface polarization frequency. By analyzing the experimental data and studying the polarization mechanism of coal in a sodium chloride solution, this study proposed an enhanced model that integrates the aspects of the Cole-Cole model and the Warburg model to overcome the limitations of the traditional first-order model, which can fit only single-peak curves. The second-order series Cole-Cole model not only delves into microscopic mechanisms underlying the low-frequency polarization effect of coal samples but also provides a highly accurate fit for complex resistivity dispersion curves under varying conditions. This research offers both an experimental foundation and a theoretical framework for leveraging the electrical properties of anthracite coal reservoirs in assessing the pore structure and permeability of coal seams.
为了研究无烟煤储层的电响应特性及其与含水饱和度、矿化度和孔隙度的相关性,在1Hz至100kHz的频率范围内测量了赵固二矿无烟煤的复电阻率。实验结果表明,随着含水饱和度、矿化度和孔隙度的增加,煤样复电阻实部和虚部的幅值均逐渐减小,导致频散程度降低,界面极化频率升高。通过分析实验数据并研究煤在氯化钠溶液中的极化机理,本研究提出了一种增强模型,该模型整合了Cole-Cole模型和Warburg模型的各方面内容,以克服传统一阶模型只能拟合单峰曲线的局限性。二阶串联Cole-Cole模型不仅深入探讨了煤样低频极化效应的微观机制,而且在不同条件下为复电阻率频散曲线提供了高精度拟合。本研究为利用无烟煤储层电性质评估煤层孔隙结构和渗透率提供了实验基础和理论框架。